Evidence map›Paper›PMID 25398144›Full record

ArticleJournal of the American Chemical Society2014

Simple, chemoselective, catalytic olefin isomerization.

Steven W M Crossley, Francis Barabé, Ryan A Shenvi

Erratum issuedAbstract read
In one paragraph

Article in Journal of the American Chemical Society, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 115 papers.

0numbers the graph read from it
0cells of the map it votes in
115citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

115 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Article
  6. Studies toward the Caged Sesquiterpenoid Daphnepapytone A.The Journal of organic chemistry · 2026
    Article
  7. Article
  8. Asymmetric Total Synthesis of (-)-Verrucarol.Angewandte Chemie (International ed. in English) · 2026
    Article
  9. Article
  10. PotassiumACS omega · 2026
    Article
  11. Article
  12. Article
  13. Effect of the [Fe(salen)]Inorganic chemistry · 2026
    Article
  14. Article
  15. Article
  16. Article
  17. HighlyThe Journal of organic chemistry · 2025
    Article
  18. Article
  19. Article
  20. Review

55 more citing papers are in PubMed but not listed here.

4 · The record

Corrections and comments

5 · Who and what money

Authors and funding

3 authors.

Steven W M CrossleyDepartment of Chemistry, The Scripps Research Institute , La Jolla, California 92037, United States.
Francis Barabé
Ryan A Shenvi

Funding

New Methods and Strategies for the Synthesis of Anticancer AlkaloidsR01GM104180 · NIGMS · SCRIPPS RESEARCH INSTITUTE, THE · PI SHENVI, RYAN ASHOK · 2013 to 2016
$1.4M
NIGMS NIH HHS GM104180NIGMS NIH HHS R01 GM104180
6 · The paper itself

Abstract

Catalytic amounts of Co(Sal(tBu,tBu))Cl and organosilane irreversibly isomerize terminal alkenes by one position. The same catalysts effect cycloisomerization of dienes and retrocycloisomerization of strained rings. Strong Lewis bases like amines and imidazoles, and labile functionalities like epoxides, are tolerated.

Indexed as

AlkenesCatalysisCobaltMolecular ConformationOrganometallic CompoundsSilanesStereoisomerismAlkenesCobaltOrganometallic CompoundsSilanes

Identifiers

PMID25398144
PMCPMC4277770

What OpenQuestion holds

Textmetadata
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.