ArticleOrganic letters2014
Regioselective allene hydroarylation via one-pot allene hydrosilylation/Pd-catalyzed cross-coupling.
Article in Organic letters, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Copper-catalyzed regio- and stereo-selective hydrosilylation of terminal allenes to access (E)-allylsilanes.Nature communications · 2022Article
- A Green Synthesis Strategy of Binuclear Catalyst for the C-C Cross-Coupling Reactions in the Aqueous Medium: Hiyama and Suzuki-Miyaura Reactions as Case Studies.Frontiers in chemistry · 2021Article
- Different reactivity of phosphorylallenes under the action of Brønsted or Lewis acids: a crucial role of involvement of the P=O group in intra- or intermolecular interactions at the formation of cationic intermediates.Beilstein journal of organic chemistry · 2019Article
- Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes.Nature communications · 2017Article
- Synthesis of Secondary and Tertiary Alkylboranes via Formal Hydroboration of Terminal and 1,1-Disubstituted Alkenes.Organic letters · 2016Article
- Regiocontrol in catalytic reductive couplings through alterations of silane rate dependence.Journal of the American Chemical Society · 2015Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
Advances in hydroarylation have been achieved by the development of a one-pot regioselective allene hydrosilylation/Pd(0)-catalyzed cross-coupling protocol. The regioselectivity is primarily governed by N-heterocyclic carbene (NHC) ligand identity in the hydrosilylation step and is preserved in the subsequent cross-coupling reaction. This methodology affords streamlined access to functionalized 1,1-disubstituted alkenes with excellent regiocontrol.
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Registered trials
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