ArticleJournal of the American Chemical Society2014
Vicinal diamination of alkenes under Rh-catalysis.
Article in Journal of the American Chemical Society, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 25 papers.
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Who cites it
25 citing papers in PubMed.
- Ring Opening of Aziridines by Pendant Sulfamates Allows for Regioselective and Stereospecific Preparation of Vicinal Diamines.The Journal of organic chemistry · 2023Article
- [3 + 2] Cycloadditions of Tertiary AmineOrganic letters · 2023Article
- Modular and practical diamination of allenes.Nature communications · 2023Article
- The advent of electrophilic hydroxylamine-derived reagents for the direct preparation of unprotected amines.Chemical communications (Cambridge, England) · 2022Review
- Aziridination Reactivity of a Manganese(II) Complex with a Bulky Chelating Bis(Alkoxide) Ligand.Molecules (Basel, Switzerland) · 2022Article
- Synthesis of Unsymmetrical Vicinal Diamines via Directed Hydroamination.Organic letters · 2022Article
- α-Diimine synthesisChemical science · 2022Article
- Photoinduced Olefin Diamination with Alkylamines.Angewandte Chemie (International ed. in English) · 2020Article
- Rhodium(III)-Catalyzed Three-Component 1,2-Diamination of Unactivated Terminal Alkenes.Synthesis · 2020Article
- Practical and stereoselective electrocatalytic 1,2-diamination of alkenes.Nature communications · 2019Article
- Gram-scale total synthesis of teixobactin promoting binding mode study and discovery of more potent antibiotics.Nature communications · 2019Article
- A general, electrocatalytic approach to the synthesis of vicinal diamines.Nature protocols · 2018Article
- Iron-Catalyzed Direct Olefin Diazidation via Peroxyester Activation Promoted by Nitrogen-Based Ligands.ACS catalysis · 2018Article
- Regiodivergent Iridium(III)-Catalyzed Diamination of Alkenyl Amides with Secondary Amines: Complementary Access to γ- or δ-Lactams.Journal of the American Chemical Society · 2018Article
- Process Safety Assessment of the Iron-Catalyzed Direct Olefin Diazidation for the Expedient Synthesis of Vicinal Primary Diamines.Organic process research & development · 2017Article
- Copper-Catalyzed Alkene Aminoazidation as a Rapid Entry to 1,2-Diamines and Installation of an Azide Reporter onto Azahetereocycles.Journal of the American Chemical Society · 2017Article
- Stereoselective Synthesis of Isoxazolidines via Copper-Catalyzed Alkene Diamination.ACS catalysis · 2017Article
- Elucidation of the Teixobactin Pharmacophore.ACS chemical biology · 2016Article
- Reductive Umpolung of Carbonyl Derivatives with Visible-Light Photoredox Catalysis: Direct Access to Vicinal Diamines and Amino Alcohols via α-Amino Radicals and Ketyl Radicals.Angewandte Chemie (International ed. in English) · 2016Article
- Asymmetric Palladium-Catalyzed Alkene Carboamination Reactions for the Synthesis of Cyclic Sulfamides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2016Article
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4 authors.
Funding
Abstract
The synthesis of 1,2-diamines has been achieved through a single-step, tandem sequence involving Rh-catalyzed aziridination followed by NaI-promoted rearrangement to an isomeric cyclic sulfamide. Facile ring opening of these products in hot water and pyridine affords differentially protected vicinal diamines. Demonstration of the utility of this method for the syntheses of (±)-enduracididine and (±)-allo-enduracididine is highlighted.
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