ArticleJournal of fluorescence2014
"Estimation of ground and excited state dipole moments of aryl boronic acid derivative by solvatochromic shift method".
Article in Journal of fluorescence, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Solvatochromic, spectroscopic, DFT calculations, antimicrobial and docking studies of new Fe(III), Co(II), and Ni(II) chelates containing 1,2,4-triazine.Scientific reports · 2026Article
- Estimation of Electric Dipole Moment by Solvatochromism, Computational Method, and Study of the Effect of Solvents by Preferential Solvation of 6 - Methoxy-4-(4-Nitro-Phenoxy Methyl)-Chromen-2-One (6mnpm).Journal of fluorescence · 2025Article
- Ground and Excited State Dipole Moments of Metformin Hydrochloride using Solvatochromic Effects and Density Functional Theory.Journal of fluorescence · 2024Article
- Modulation of benzofuran structure as a fluorescent probe to optimize linear and nonlinear optical properties and biological activities.Journal of molecular modeling · 2020Article
- Estimation of Dipole Moments and Quantum Yield of 5-chloro-2-methoxyphenyl Boronic Acid in Different Solvents Environment.Journal of fluorescence · 2015Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
In the present work, the absorption and fluorescence spectra of newly synthesized aryl boronic acid derivative namely 2-Methylphenyl boronic acid (2MPBA) have been recorded in various solvents of different polarities. The ground state dipole moment of 2MPBA was obtained from quantum chemical calculations. Solvatochromic correlations were used to estimate the ground state (μ g ) and excited state (μ e ) dipole moments. The excited state dipole moments are observed to be greater than the ground state dipole moment and ground and excited state dipole moments are not parallel but subtend by an angle of 88(0). Further, the changes in dipole moment (Δμ) were calculated both from solvatochromic shift method and microscopic solvent polarity parameter (E T (N) ), and the value are compared. The spectral variations were analyzed by Kamlet-Taft parameters.
Identifiers
25231695What OpenQuestion holds
Registered trials
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