ArticleScientific reports2014
Honeycomb-like porous gel polymer electrolyte membrane for lithium ion batteries with enhanced safety.
Article in Scientific reports, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
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Who cites it
22 citing papers in PubMed.
- Cholesteric Liquid Crystal Elastomer-Based Single-Ion Conductor for Advanced Quasi-Solid Electrolyte Membranes.Molecules (Basel, Switzerland) · 2026Article
- Fabrication and Performance Study of 3D-Printed Ceramic-in-Gel Polymer Electrolytes.Gels (Basel, Switzerland) · 2025Article
- Photo-Crosslinked Polyurethane-Containing Gel Polymer Electrolytes via Free-Radical Polymerization Method.Polymers · 2024Article
- A Comprehensive Review of Functional Gel Polymer Electrolytes and Applications in Lithium-Ion Battery.Gels (Basel, Switzerland) · 2024Review
- MXene Clay (Ti2C)-Containing In Situ Polymerized Hollow Core-Shell Binder for Silicon-Based Anodes in Lithium-Ion Batteries.ACS omega · 2023Article
- Review
- Electrolyte Design for Lithium Metal Anode-Based Batteries Toward Extreme Temperature Application.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2021Review
- PVDF HFP_RuONanomaterials (Basel, Switzerland) · 2021Article
- Ultrasound-Assisted Hydroxyapatite-Decorated Breath-Figure Polymer-Derived Ceramic Coatings for Ti6Al4V Substrates.ACS applied materials & interfaces · 2020Article
- Article
- Article
- Differentiated Lithium Salt Design for Multilayered PEO Electrolyte Enables a High-Voltage Solid-State Lithium Metal Battery.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2019Article
- Theoretical and Experimental Sets of Choice Anode/Cathode Architectonics for High-Performance Full-Scale LIB Built-up Models.Nano-micro letters · 2019Article
- In Search of a Green Process: Polymeric Films with Ordered Arrays via a Water Droplet Technique.Polymers · 2019Review
- High Performance Poly(vinyl alcohol)-Based Li-Ion Conducting Gel Polymer Electrolyte Films for Electric Double-Layer Capacitors.Polymers · 2018Article
- Recent Advances in Poly(vinylidene fluoride) and Its Copolymers for Lithium-Ion Battery Separators.Membranes · 2018Review
- Porous (PVDF-HFP/PANI/GO) ternary hybrid polymer electrolyte membranes for lithium-ion batteries.RSC advances · 2018Article
- Ionic Conductivity and Cycling Stability Improvement of PVDF/Nano-Clay Using PVP as Polymer Electrolyte Membranes for LiFePO₄ Batteries.Membranes · 2018Article
- Confining electrodeposition of metals in structured electrolytes.Proceedings of the National Academy of Sciences of the United States of America · 2018Article
- Nanoporous UHMWPE Membrane Separators for Safer and High-Power-Density Rechargeable Batteries.Global challenges (Hoboken, NJ) · 2017Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Lithium ion batteries have shown great potential in applications as power sources for electric vehicles and large-scale energy storage. However, the direct uses of flammable organic liquid electrolyte with commercial separator induce serious safety problems including the risk of fire and explosion. Herein, we report the development of poly(vinylidene difluoride-co-hexafluoropropylene) polymer membranes with multi-sized honeycomb-like porous architectures. The as-prepared polymer electrolyte membranes contain porosity as high as 78%, which leads to the high electrolyte uptake of 86.2 wt%. The PVDF-HFP gel polymer electrolyte membranes exhibited a high ionic conductivity of 1.03 mS cm(-1) at room temperature, which is much higher than that of commercial polymer membranes. Moreover, the as-obtained gel polymer membranes are also thermally stable up to 350 °C and non-combustible in fire (fire-proof). When applied in lithium ion batteries with LiFePO4 as cathode materials, the gel polymer electrolyte demonstrated excellent electrochemical performances. This investigation indicates that PVDF-HFP gel polymer membranes could be potentially applicable for high power lithium ion batteries with the features of high safety, low cost and good performance.
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Registered trials
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