ArticleOrganic letters2014
Cobalt-catalyzed, aminoquinoline-directed coupling of sp(2) C-H bonds with alkenes.
Article in Organic letters, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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Who cites it
18 citing papers in PubMed.
- Mechanistic Investigations of Cobalt-Catalyzed, Aminoquinoline-Directed C(spJournal of the American Chemical Society · 2025Article
- Cobalt-catalyzed radical-mediated carbon-carbon scissionChemical science · 2023Article
- Hexafluoroisopropanol: the magical solvent for Pd-catalyzed C-H activation.Chemical science · 2021Review
- Article
- Direct Regio- and Diastereoselective Synthesis of δ-Lactams from Acrylamides and Unactivated Alkenes Initiated by RhAngewandte Chemie (International ed. in English) · 2020Article
- Co-catalyzedRSC advances · 2019Article
- Asymmetric δ-Lactam Synthesis with a Monomeric Streptavidin Artificial Metalloenzyme.Journal of the American Chemical Society · 2019Article
- Cobalt-catalyzed electrooxidative C-H/N-H [4+2] annulation with ethylene or ethyne.Nature communications · 2018Article
- Cobalt-Catalyzed Coupling of Benzoic Acid C-H Bonds with Alkynes, Styrenes, and 1,3-Dienes.Angewandte Chemie (International ed. in English) · 2018Article
- Introducing unactivated acyclic internal aliphatic olefins into a cobalt catalyzed allylic selective dehydrogenative Heck reaction.Chemical science · 2017Article
- Aminoquinoline-directed, cobalt-catalyzed carbonylation of sulfonamide spChemical communications (Cambridge, England) · 2017Article
- Highly Stereoselective Cobalt(III)-Catalyzed Three-Component C-H Bond Addition Cascade.Angewandte Chemie (International ed. in English) · 2016Article
- Cobalt-Catalyzed, Aminoquinoline-Directed Functionalization of Phosphinic Amide spACS catalysis · 2016Article
- Cobalt(III)-Catalyzed C-H Bond Amidation with Isocyanates.Organic letters · 2015Article
- Bidentate, monoanionic auxiliary-directed functionalization of carbon-hydrogen bonds.Accounts of chemical research · 2015Article
- Cobalt-promoted dimerization of aminoquinoline benzamides.Organic letters · 2015Article
- Cobalt(III)-catalyzed synthesis of indazoles and furans by C-H bond functionalization/addition/cyclization cascades.Journal of the American Chemical Society · 2015Article
- Cobalt-catalyzed direct carbonylation of aminoquinoline benzamides.Organic letters · 2014Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
A method for cobalt-catalyzed, aminoquinoline-directed ortho-functionalization of sp(2) C-H bonds with alkenes has been developed. Reactions proceed at room temperature in trifluoroethanol solvent, use oxygen from air as an oxidant, and require Mn(OAc)3 as a cocatalyst. Benzoic, heteroaromatic, and acrylic acid aminoquinoline amides react with ethylene as well as mono- and disubstituted alkenes affording products in good yields. Excellent functional group tolerance is observed; halogen, nitro, ether, and unprotected alcohol functionalities are compatible with the reaction conditions.
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