ArticleJournal of the American Chemical Society2014
Enantioselective olefin metathesis with cyclometalated ruthenium complexes.
Article in Journal of the American Chemical Society, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- Construction of quaternary stereocenters via Ru-catalyzed asymmetric ring-closing metathesis.Nature communications · 2026Article
- Article
- Chiral-at-metal catalysts: history, terminology, design, synthesis, and applications.Chemical Society reviews · 2025Review
- Asymmetric Photoaerobic Lactonization and Aza-Wacker Cyclization of Alkenes Enabled by Ternary Selenium-Sulfur Multicatalysis.ACS catalysis · 2023Article
- Metal Stereogenicity in Asymmetric Transition Metal Catalysis.Chemical reviews · 2023Review
- Article
- Catalysis with cycloruthenated complexes.Chemical science · 2022Review
- Asymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity.Nature communications · 2020Article
- Light-Activated Olefin Metathesis: Catalyst Development, Synthesis, and Applications.Accounts of chemical research · 2020Article
- Bis-Cyclometalated Indazole Chiral-at-Rhodium Catalyst for Asymmetric Photoredox Cyanoalkylations.Chemistry (Weinheim an der Bergstrasse, Germany) · 2019Article
- Recent advances in the application of ring-closing metathesis for the synthesis of unsaturated nitrogen heterocycles.Synthesis · 2019Article
- Article
- Recent advances in ruthenium-based olefin metathesis.Chemical Society reviews · 2018Review
- An Initiation Kinetics Prediction Model Enables Rational Design of Ruthenium Olefin Metathesis Catalysts Bearing Modified Chelating Benzylidenes.ACS catalysis · 2018Article
- Preparation of chiral-at-metal catalysts and their use in asymmetric photoredox chemistry.Nature protocols · 2018Article
- Cationic ruthenium alkylidene catalysts bearing phosphine ligands.Dalton transactions (Cambridge, England : 2003) · 2016Article
- Tandem Z-Selective Cross-Metathesis/Dihydroxylation: Synthesis of anti-1,2-Diols.Angewandte Chemie (International ed. in English) · 2015Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
The success of enantioselective olefin metathesis relies on the design of enantioenriched alkylidene complexes capable of transferring stereochemical information from the catalyst structure to the reactants. Cyclometalation of the NHC ligand has proven to be a successful strategy to incorporate stereogenic atoms into the catalyst structure. Enantioenriched complexes incorporating this design element catalyze highly Z- and enantioselective asymmetric ring opening/cross metathesis (AROCM) of norbornenes and cyclobutenes, and the difference in ring strain between these two substrates leads to different propagating species in the catalytic cycle. Asymmetric ring closing metathesis (ARCM) of a challenging class of prochiral trienes has also been achieved. The extent of reversibility and effect of reaction setup was also explored. Finally, promising levels of enantioselectivity in an unprecedented Z-selective asymmetric cross metathesis (ACM) of a prochiral 1,4-diene was demonstrated.
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