ArticleOrganic letters2014
Activation of alcohols with carbon dioxide: intermolecular allylation of weakly acidic pronucleophiles.
Article in Organic letters, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
6 citing papers in PubMed, 56 citations in OpenAlex.
- Cobalt-Catalyzed Decarboxylative Allylations: Development and Mechanistic Studies.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Photocatalytic synthesis of tetra-substituted furans promoted by carbon dioxide.Chemical science · 2021Article
- Toward ideal carbon dioxide functionalization.Chemical science · 2019Review
- Stereoselective synthesis of sulfur-containing β-enaminonitrile derivatives through electrochemical CspNature communications · 2019Article
- On the direct use of CORSC advances · 2018Article
- EtBeilstein journal of organic chemistry · 2016Article
Corrections and comments
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
Abstract
The direct coupling of allyl alcohols with nitroalkanes, nitriles, and aldehydes using catalytic Pd(PPh3)4 has been accomplished via activation of C-OH bonds with CO2. The in situ formation of carbonates from alcohols and CO2 facilitates oxidative addition to Pd to form reactive π-allylpalladium intermediates. In addition, the formation of a strong base activates nucleophiles toward the reaction with the π-allylpalladium electrophile. Overall, this atom economical reaction provides a new C-C bond without the use of an external base and generates water as the only byproduct.
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Registered trials
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