ArticleAngewandte Chemie (International ed. in English)2014
Simple sulfinate synthesis enables C-H trifluoromethylcyclopropanation.
Article in Angewandte Chemie (International ed. in English), 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 35 papers.
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Who cites it
35 citing papers in PubMed.
- Enabling Fluoroalkyl-Sulfonylalkylation and Fluoroalkyl-Halogenation of Alkenes and Alkynes via Photoredox Catalysis.Journal of the American Chemical Society · 2026Article
- Harnessing COJournal of the American Chemical Society · 2026Article
- A Photocatalytic Approach to Radical 1-(Trifluoromethyl)cyclopropanation.ACS catalysis · 2025Article
- Reductive sulfinylation by nucleophilic chain isomerization of sulfonylpyridinium.Nature communications · 2025Article
- CFJACS Au · 2024Article
- Electrochemical deoxygenative amination of stabilized alkyl radicals from activated alcohols.Nature communications · 2024Article
- Alcohol-alcohol cross-coupling enabled by SScience (New York, N.Y.) · 2024Article
- Fluorescent labeling of RNA and DNA on the Hoogsteen edge using sulfinate chemistry.RNA (New York, N.Y.) · 2023Article
- Alkyl sulfinates as cross-coupling partners for programmable and stereospecific installation of C(spNature chemistry · 2023Article
- Reductant-Free Cross-Electrophile Synthesis of Di(hetero)arylmethanes by Palladium-Catalyzed Desulfinative C-C Coupling.Angewandte Chemie (International ed. in English) · 2022Article
- Functional group divergence and the structural basis of acridine photocatalysis revealed by direct decarboxysulfonylation.Chemical science · 2022Article
- Photons or Electrons? A Critical Comparison of Electrochemistry and Photoredox Catalysis for Organic Synthesis.Chemical reviews · 2022Review
- Synthesis and applications of sodium sulfinates (RSORSC advances · 2021Review
- Silyloxymethanesulfinate as a sulfoxylate equivalent for the modular synthesis of sulfones and sulfonyl derivatives.Chemical science · 2020Article
- Decarboxylative thiolation of redox-active esters to free thiols and further diversification.Nature communications · 2020Article
- Cubane Electrochemistry: Direct Conversion of Cubane Carboxylic Acids to Alkoxy Cubanes Using the Hofer-Moest Reaction under Flow Conditions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- C-H Halogenation of Pyridyl Sulfides Avoiding the Sulfur Oxidation: A Direct Catalytic Access to Sulfanyl Polyhalides and Polyaromatics.ACS omega · 2019Article
- A novel photoredox-active group for the generation of fluorinated radicals from difluorostyrenes.Chemical science · 2019Article
- Upcycling aromatic polymers through C-H fluoroalkylation.Chemical science · 2019Article
- Visible-light-mediated Minisci C-H alkylation of heteroarenes with unactivated alkyl halides using OChemical science · 2019Article
Corrections and comments
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Authors and funding
8 authors.
Funding
Abstract
A simple method to convert readily available carboxylic acids into sulfinate salts by employing an interrupted Barton decarboxylation reaction is reported. A medicinally oriented panel of ten new sulfinate reagents was created using this method, including a key trifluoromethylcyclopropanation reagent, TFCS-Na. The reactivity of six of these salts towards C-H functionalization was field-tested using several different classes of heterocycles.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.