Evidence map›Paper›PMID 25068072›Full record

ArticleACS catalysis2014

Palladium-Catalyzed Intra- and Intermolecular C-H Arylation Using Mesylates: Synthetic Scope and Mechanistic Studies.

Devin M Ferguson, Stacey R Rudolph, Dipannita Kalyani

Abstract read
In one paragraph

Article in ACS catalysis, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Devin M FergusonDepartment of Chemistry, St. Olaf College , 1520 St. Olaf Ave, Northfield, Minnesota 55057, United States.
Stacey R RudolphDepartment of Chemistry, St. Olaf College , 1520 St. Olaf Ave, Northfield, Minnesota 55057, United States.
Dipannita KalyaniDepartment of Chemistry, St. Olaf College , 1520 St. Olaf Ave, Northfield, Minnesota 55057, United States.

Funding

Palladium and Nickel Catalyzed C-H Activation/C-C Bond FormationR15GM107892 · NIGMS · ST. OLAF COLLEGE · PI KALYANI, DIPANNITA · 2013 to 2013
$281k
NIGMS NIH HHS R15 GM107892
6 · The paper itself

Abstract

This paper describes the development of Pd-catalyzed inter- and intramolecular direct arylation using mesylates. Furthermore, a sequential mesylation/arylation protocol using phenols as substrates is described. These transformations are general with respect to the electronics of the C-H substrates and allow for the synthesis of diverse heterocyclic motifs in good yields. Both arenes and heteroarenes efficiently participate in these reactions. Preliminary mechanistic studies are presented for both inter- and intramolecular arylations.

Indexed as

arylationC−H activationhomogeneous catalysismesylatespalladium

Identifiers

PMID25068072
PMCPMC4105186

What OpenQuestion holds

Textmetadata
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.