ArticleJournal of the American Chemical Society2014
Rapid synthesis of polyprenylated acylphloroglucinol analogs via dearomative conjunctive allylic annulation.
Article in Journal of the American Chemical Society, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Advances in natural product discovery: strategies, technologies, and insights.Natural products and bioprospecting · 2026Review
- Total Synthesis of (-)-Elodeoidins A and B.JACS Au · 2025Article
- Article
- Dearomative logic in natural product total synthesis.Natural product reports · 2022Review
- Biomimetic Synthesis of Meroterpenoids by Dearomatization-Driven Polycyclization.Angewandte Chemie (International ed. in English) · 2019Article
- Regiodivergent Photocyclization of Dearomatized Acylphloroglucinols: Asymmetric Syntheses of (-)-Nemorosone and (-)-6-Journal of the American Chemical Society · 2019Article
- Successive Nucleophilic and Electrophilic Allylation for the Catalytic Enantioselective Synthesis of 2,4-Disubstituted Pyrrolidines.Organic letters · 2019Article
- Tsuji-Trost Cyclization of Disulfonamides: Synthesis of 12-Membered, 11-Membered, and Pyridine-Fused Macrocyclic Triamines.ACS omega · 2019Article
- Prenyl Praxis: A Method for Direct Photocatalytic Defluoroprenylation.Journal of the American Chemical Society · 2018Article
- Hyperjaponol H, A New Bioactive Filicinic Acid-Based Meroterpenoid from Hypericum japonicum Thunb. ex Murray.Molecules (Basel, Switzerland) · 2018Article
- Arenophile-Mediated Dearomative Reduction.Angewandte Chemie (International ed. in English) · 2016Article
- Hyperisampsins H-M, Cytotoxic Polycyclic Polyprenylated Acylphloroglucinols from Hypericum sampsonii.Scientific reports · 2015Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
Polyprenylated acylphloroglucinols (PPAPs) are structurally complex natural products with promising biological activities. Herein, we present a biosynthesis-inspired, diversity-oriented synthesis approach for rapid construction of PPAP analogs via double decarboxylative allylation (DcA) of acylphloroglucinol scaffolds to access allyl-desoxyhumulones followed by dearomative conjunctive allylic alkylation (DCAA).
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.