ArticleAngewandte Chemie (International ed. in English)2014
Ligand modification transforms a catalase mimic into a water oxidation catalyst.
Article in Angewandte Chemie (International ed. in English), 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
15 citing papers in PubMed, 143 citations in OpenAlex.
- Dipyridinophane ligands - synthesis and coordination study.RSC advances · 2026Article
- Comparative Nitrene-Transfer Chemistry to Olefins Mediated by First-Row Transition Metal Catalysts Supported by a Pyridinophane Macrocycle with N4 Ligation.Molecules (Basel, Switzerland) · 2025Article
- Synthesis and Characterization of Bipyridyl-(Imidazole)Molecules (Basel, Switzerland) · 2023Article
- Synthesis and characterization of two piperazine containing macrocycles and their transition metal complexes.Journal of inorganic biochemistry · 2023Article
- Two Novel Schiff Base Manganese Complexes as Bifunctional Electrocatalysts for COMolecules (Basel, Switzerland) · 2023Article
- Manganese (III/IV) μ-Oxo Dimers and Manganese (III) Monomers with Tetraaza Macrocyclic Ligands and Historically Relevant Open-Chain Ligands.European journal of inorganic chemistry · 2022Article
- Ligands modification strategies for mononuclear water splitting catalysts.Frontiers in chemistry · 2022Review
- Electrocatalytic Water Oxidation with α-[Fe(mcp)(OTf)ACS catalysis · 2021Article
- Switching the O-O Bond Formation Pathways of Ru-pda Water Oxidation Catalyst by Third Coordination Sphere Engineering.Research (Washington, D.C.) · 2021Article
- Controlled hierarchical self-assembly of networked coordination nanocapsulesChemical science · 2020Article
- Hydrogen Peroxide Disproportionation with Manganese Macrocyclic Complexes of Cyclen and Pyclen.Inorganic chemistry frontiers · 2020Article
- Enhancement of the Antioxidant Activity and Neurotherapeutic Features through Pyridol Addition to Tetraazamacrocyclic Molecules.Inorganic chemistry · 2019Article
- Improved synthesis of symmetrically & asymmetrically N-substituted pyridinophane derivatives.Organic & biomolecular chemistry · 2017Article
- A Dinuclear Ruthenium-Based Water Oxidation Catalyst: Use of Non-Innocent Ligand Frameworks for Promoting Multi-Electron Reactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2015Article
- Origin and Evolution of Water Oxidation before the Last Common Ancestor of the Cyanobacteria.Molecular biology and evolution · 2015Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors at 2 institutions in 1 country.
Funding
Abstract
The catalytic reactivity of the high-spin Mn(II) pyridinophane complexes [(Py2NR2)Mn(H2O)2](2+) (R=H, Me, tBu) toward O2 formation is reported. With small macrocycle N-substituents (R=H, Me), the complexes catalytically disproportionate H2O2 in aqueous solution; with a bulky substituent (R=tBu), this catalytic reaction is shut down, but the complex becomes active for aqueous electrocatalytic H2O oxidation. Control experiments are in support of a homogeneous molecular catalyst and preliminary mechanistic studies suggest that the catalyst is mononuclear. This ligand-controlled switch in catalytic reactivity has implications for the design of new manganese-based water oxidation catalysts.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.