Evidence map›Paper›PMID 24981531›Full record

ArticleThe Journal of chemical physics2013

Multidimensional x-ray spectroscopy of valence and core excitations in cysteine.

Jason D Biggs, Yu Zhang, Daniel Healion, Shaul Mukamel

Open access · greenAbstract read
In one paragraph

Article in The Journal of chemical physics, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
3.6field-weighted citation impact, top 7% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed, 24 citations in OpenAlex.

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  7. Watching energy transfer in metalloporphyrin heterodimers using stimulated X-ray Raman spectroscopy.Proceedings of the National Academy of Sciences of the United States of America · 2013
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 1 institution in 1 country.

Jason D BiggsDepartment of Chemistry, University of California, 450 Rowland Hall, Irvine, California 92697, USA.
Yu ZhangDepartment of Chemistry, University of California, 450 Rowland Hall, Irvine, California 92697, USA.
Daniel HealionDepartment of Chemistry, University of California, 450 Rowland Hall, Irvine, California 92697, USA.
Shaul MukamelDepartment of Chemistry, University of California, 450 Rowland Hall, Irvine, California 92697, USA.
University of California, Irvine · US

Funding

Multidimensional Femtosecond Correlation Spectroscopic Probes of BiomoleculesR01GM059230 · NIGMS · UNIVERSITY OF ROCHESTER · PI MUKAMEL, SHAUL · 2001 to 2013
$3.2M
NIGMS NIH HHS GM-59230NIGMS NIH HHS R01 GM059230
6 · The paper itself

Abstract

Several nonlinear spectroscopy experiments which employ broadband x-ray pulses to probe the coupling between localized core and delocalized valence excitation are simulated for the amino acid cysteine at the K-edges of oxygen and nitrogen and the K- and L-edges of sulfur. We focus on two-dimensional (2D) and 3D signals generated by two- and three-pulse stimulated x-ray Raman spectroscopy (SXRS) with frequency-dispersed probe. We show how the four-pulse x-ray signals [Formula: see text] and [Formula: see text] can give new 3D insight into the SXRS signals. The coupling between valence- and core-excited states can be visualized in three-dimensional plots, revealing the origin of the polarizability that controls the simpler pump-probe SXRS signals.

Indexed as

Spectrum Analysis, RamanCysteineNitrogenOxygenX-Ray Absorption SpectroscopyCysteineNitrogenOxygen

Identifiers

PMID24981531
PMCPMC3637361
OpenAlexW2130429876

What OpenQuestion holds

Textmetadata
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.