ArticleNature communications2014
Regulating proton-coupled electron transfer for efficient water splitting by manganese oxides at neutral pH.
Article in Nature communications, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
18 citing papers in PubMed, 192 citations in OpenAlex.
- Steering Electron Transport in Intrinsically Piezoelectric Covalent Organic Frameworks for Efficient COAngewandte Chemie (International ed. in English) · 2026Article
- The Effect of Nanoparticle Structure on the Thermodynamics and Kinetics of Proton-Coupled Electron Transfer Reactions to V2O5.Journal of the American Chemical Society · 2026Article
- Decoding MnONature communications · 2026Article
- Polarity reversal for enhancedElectrochimica acta · 2023Article
- High Current Density Oxygen Evolution in Carbonate Buffered Solution Achieved by Active Site Densification and Electrolyte Engineering.ChemSusChem · 2023Article
- Constructing NiSeRSC advances · 2021Article
- Tuning of lattice oxygen reactivity and scaling relation to construct better oxygen evolution electrocatalyst.Nature communications · 2021Article
- Water-Assisted Concerted Proton-Electron Transfer at Co(II)-Aquo Sites in Polyoxotungstates With Photogenerated RuChemphyschem : a European journal of chemical physics and physical chemistry · 2021Article
- Delivering the Full Potential of Oxygen Evolving Electrocatalyst by Conditioning Electrolytes at Near-Neutral pH.ChemSusChem · 2021Article
- Molecular Functionalization of NiO Nanocatalyst for Enhanced Water Oxidation by Electronic Structure Engineering.ChemSusChem · 2020Article
- Tuning proton-coupled electron transfer by crystal orientation for efficient water oxidization on double perovskite oxides.Nature communications · 2020Article
- Enhanced stability and ultrahigh activity of amorphous ripple nanostructured Ni-doped Fe oxyhydroxide electrode toward synergetic electrocatalytic water splitting.RSC advances · 2020Article
- Efficient BiVOAngewandte Chemie (International ed. in English) · 2019Article
- Electrochemical characterization of manganese oxides as a water oxidation catalyst in proton exchange membrane electrolysers.Royal Society open science · 2019Article
- Manganese(ii) phosphate nanosheet assembly with native out-of-plane Mn centres for electrocatalytic water oxidation.Chemical science · 2019Article
- Theory-driven design of high-valence metal sites for water oxidation confirmed using in situ soft X-ray absorption.Nature chemistry · 2018Article
- Towards Versatile and Sustainable Hydrogen Production through Electrocatalytic Water Splitting: Electrolyte Engineering.ChemSusChem · 2017Review
- Implementation of concurrent electrolytic generation of two homogeneous mediators under widened potential conditions to facilitate removal of air-pollutants.Scientific reports · 2017Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
6 authors at 3 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Manganese oxides have been extensively investigated as model systems for the oxygen-evolving complex of photosystem II. However, most bioinspired catalysts are inefficient at neutral pH and functional similarity to the oxygen-evolving complex has been rarely achieved with manganese. Here we report the regulation of proton-coupled electron transfer involved in water oxidation by manganese oxides. Pyridine and its derivatives, which have pKa values intermediate to the water ligand bound to manganese(II) and manganese(III), are used as proton-coupled electron transfer induction reagents. The induction of concerted proton-coupled electron transfer is demonstrated by the detection of deuterium kinetic isotope effects and compliance of the reactions with the libido rule. Although proton-coupled electron transfer regulation is essential for the facial redox change of manganese in photosystem II, most manganese oxides impair these regulatory mechanisms. Thus, the present findings may provide a new design rationale for functional analogues of the oxygen-evolving complex for efficient water splitting at neutral pH.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.