ArticleAngewandte Chemie (International ed. in English)2014
Cyclodextrin-templated porphyrin nanorings.
Article in Angewandte Chemie (International ed. in English), 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Highly Rigid, Yet Conformationally Adaptable, BisporphyrinJournal of the American Chemical Society · 2025Article
- Chiral Induction of a Tetrakis(porphyrin) in Various Chiral Solvents.Chemistry (Weinheim an der Bergstrasse, Germany) · 2024Article
- Self-Assembly of Chiral Cyclohexanohemicucurbit[Molecules (Basel, Switzerland) · 2022Article
- A Complex Comprising a Cyanine Dye Rotaxane and a Porphyrin Nanoring as a Model Light-Harvesting System.Angewandte Chemie (International ed. in English) · 2020Article
- Synthesis of Five-Porphyrin Nanorings by Using Ferrocene and Corannulene Templates.Angewandte Chemie (International ed. in English) · 2016Article
- Self-Assembly of Russian Doll Concentric Porphyrin Nanorings.Journal of the American Chemical Society · 2015Article
- Caterpillar Track Complexes in Template-Directed Synthesis and Correlated Molecular Motion.Angewandte Chemie (Weinheim an der Bergstrasse, Germany) · 2015Article
- Caterpillar track complexes in template-directed synthesis and correlated molecular motion.Angewandte Chemie (International ed. in English) · 2015Article
- Applications of dynamic combinatorial chemistry for the determination of effective molarity.Chemical science · 2015Article
- Vernier-templated synthesis, crystal structure, and supramolecular chemistry of a 12-porphyrin nanoring.Chemistry (Weinheim an der Bergstrasse, Germany) · 2014Article
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5 authors.
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Abstract
α- and β-cyclodextrins have been used as scaffolds for the synthesis of six- and seven-legged templates by functionalizing every primary CH2OH with a 4-pyridyl moiety. Although these templates are flexible, they are very effective for directing the synthesis of macrocyclic porphyrin oligomers consisting of six or seven porphyrin units. The transfer of chirality from the cyclodextrin templates to their nanoring hosts is evident from NMR and circular dichroism spectroscopy. Surprisingly, the mean effective molarity for binding the flexible α-cyclodextrin-based template within the six-porphyrin nanoring (74 M) is almost as high as for the previously studied rigid hexadentate template (180 M). The discovery that flexible templates are effective in this system, and the availability of a template with a prime number of binding sites, open up many possibilities for the template-directed synthesis of larger macrocycles.
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