ArticleProceedings of the National Academy of Sciences of the United States of America2014
Solid-state structures of peapod bearings composed of finite single-wall carbon nanotube and fullerene molecules.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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Who cites it
18 citing papers in PubMed.
- Confined Space Nanoarchitectonics for Dynamic Functions and Molecular Machines.Micromachines · 2024Review
- Recent advances in supramolecular fullerene chemistry.Chemical Society reviews · 2024Review
- Fullerene Wires Assembled Inside Carbon Nanohoops.ChemPlusChem · 2022Review
- A hybrid molecular peapod of spNature communications · 2021Article
- Conjugated Nanohoops Incorporating Donor, Acceptor, Hetero- or Polycyclic Aromatics.Angewandte Chemie (International ed. in English) · 2021Review
- Stereoselectivity in spontaneous assembly of rolled incommensurate carbon bilayers.Nature communications · 2021Article
- Theoretical study on aromatic and open-shell characteristics of carbon nanobelts composed of indeno[1,2-RSC advances · 2020Article
- The Supramolecular Chemistry of Cycloparaphenylenes and Their Analogs.Frontiers in chemistry · 2019Review
- Concyclic CH-π arrays for single-axis rotations of a bowl in a tube.Nature communications · 2018Article
- Ratchet-free solid-state inertial rotation of a guest ball in a tight tubular host.Nature communications · 2018Article
- Chiral intertwined spirals and magnetic transition dipole moments dictated by cylinder helicity.Proceedings of the National Academy of Sciences of the United States of America · 2017Article
- Buckyball sandwiches.Science advances · 2017Article
- Stereoisomerism in Nanohoops with Heterogeneous Biaryl Linkages ofACS central science · 2016Article
- Stereoisomerism, crystal structures, and dynamics of belt-shaped cyclonaphthylenes.Proceedings of the National Academy of Sciences of the United States of America · 2016Article
- Cycloparaphenylene as a molecular porous carbon solid with uniform pores exhibiting adsorption-induced softness.Chemical science · 2016Article
- Reply to the 'Comment on "Theoretical studies on a carbonaceous molecular bearing: association thermodynamics and dual-mode rolling dynamics"' by E. M. Cabaleiro-Lago, J. Rodriguez-Otero and A. Gil,Chemical science · 2016Article
- Theoretical studies on a carbonaceous molecular bearing: association thermodynamics and dual-mode rolling dynamics.Chemical science · 2015Article
- Molecular recognition in curved π-systems: effects of π-lengthening of tubular molecules on thermodynamics and structures.Chemical science · 2015Article
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3 authors.
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No grant is acknowledged in the PubMed record.
Abstract
A supramolecular combination of carbon nanotube and fullerene, so-called a peapod, has attracted much interest, not solely because of its physical properties but also for its unique assembled structures of carbonaceous entities. However, the detailed structural information available was not sufficient for in-depth understanding of its structural chemistry or for exploratory research inspired by novel physical phenomena, mainly because of the severely inhomogeneous nature of currently available carbon nanotubes. We herein report solid-state structures of a molecular peapod. This structure, solved with a belt-persistent finite carbon nanotube molecule at the atomic level by synchrotron X-ray diffraction, revealed the presence of a smooth, inflection-free Hirshfeld surface inside the tube, and the smoothness permitted dynamic motion of the C60 guest molecule even in the solid state. This precise structural information may inspire the molecular design of carbonaceous machines assembled purely through van der Waals contacts between two neutral molecules.
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