ArticleAngewandte Chemie (International ed. in English)2014
Formal (4+1) cycloaddition of methylenecyclopropanes with 7-aryl-1,3,5-cycloheptatrienes by triple gold(I) catalysis.
Article in Angewandte Chemie (International ed. in English), 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- A highly diastereoselective strain-release Doyle-Kirmse reaction: access to functionalized difluoro(methylene)cyclopropanes.Chemical science · 2023Article
- Hypervalent iodine promoted the synthesis of cycloheptatrienes and cyclopropanes.Chemical science · 2022Article
- Gold-Catalyzed Synthesis of Small Rings.Chemical reviews · 2021Article
- Gold(I)-catalyzed intramolecular cyclization/intermolecular cycloaddition cascade as a fast track to polycarbocycles and mechanistic insights.Nature communications · 2021Article
- Direct Observation of Aryl Gold(I) Carbenes that Undergo Cyclopropanation, C-H Insertion, and Dimerization Reactions.Angewandte Chemie (International ed. in English) · 2019Article
- Gold(I)-Catalyzed Synthesis of Indenes and Cyclopentadienes: Access to (±)-Laurokamurene B and the Skeletons of the Cycloaurenones and Dysiherbols.Angewandte Chemie (International ed. in English) · 2017Article
- Cyclobutene vs 1,3-Diene Formation in the Gold-Catalyzed Reaction of Alkynes with Alkenes: The Complete Mechanistic Picture.Journal of the American Chemical Society · 2017Article
- StereoselectiveACS catalysis · 2017Article
- Enantiospecific Trifluoromethyl-Radical-Induced Three-Component Coupling of Boronic Esters with Furans.Angewandte Chemie (International ed. in English) · 2017Article
- Divergent reaction pathways in gold-catalyzed cycloisomerization of 1,5-enynes containing a cyclopropane ring: dramaticChemical science · 2016Article
- Gold(i)-catalyzed cycloisomerization of vinylidenecyclopropane-enesChemical science · 2015Article
- Gold carbene or carbenoid: is there a difference?Chemistry (Weinheim an der Bergstrasse, Germany) · 2015Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
7-Aryl-1,3,5-cycloheptatrienes react intermolecularly with methylenecyclopropanes in a triple gold(I)-catalyzed reaction to form cyclopentenes. The same formal (4+1) cycloaddition occurs with cyclobutenes. Other precursors of gold(I) carbenes can also be used as the C1 component of the cycloaddition.
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Registered trials
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