Evidence map›Paper›PMID 24883040›Full record

ArticleEuropean journal of organic chemistry2014

Preparation of Diversely Substituted Triarylmethyl Radicals by the Quenching of Tris(2,3,5,6-tetrathiaaryl)methyl Cations with C-, N-, P-, and S-Nucleophiles.

Victor M Tormyshev, Olga Yu Rogozhnikova, Michael K Bowman, Dmitry V Trukhin, Tatiana I Troitskaya, Vladimir G Vasiliev, Leonid A Shundrin, Howard J Halpern

Abstract read
In one paragraph

Article in European journal of organic chemistry, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Facile and High-Yielding Synthesis of TAM Biradicals and Monofunctional TAM Radicals.Synlett : accounts and rapid communications in synthetic organic chemistry · 2016
    Article
  6. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Victor M TormyshevVorozhtsov Novosibirsk Institute of Organic Chemistry, 9 Acad. M.A. Lavrentjev Ave., Novosibirsk 630090, Russia, http://www.nioch.nsc.ru/eng/labs/mcg_e.htm ; Department of Natural Sciences, National Research University, Novosibirsk State University, 2 Pirogov St., Novosibirsk 630090, Russia.
Olga Yu RogozhnikovaVorozhtsov Novosibirsk Institute of Organic Chemistry, 9 Acad. M.A. Lavrentjev Ave., Novosibirsk 630090, Russia, http://www.nioch.nsc.ru/eng/labs/mcg_e.htm.
Michael K BowmanDepartment of Chemistry, The University of Alabama, Box 870336, Tuscaloosa, Alabama 35487-0336, USA.
Dmitry V TrukhinVorozhtsov Novosibirsk Institute of Organic Chemistry, 9 Acad. M.A. Lavrentjev Ave., Novosibirsk 630090, Russia, http://www.nioch.nsc.ru/eng/labs/mcg_e.htm.
Tatiana I TroitskayaVorozhtsov Novosibirsk Institute of Organic Chemistry, 9 Acad. M.A. Lavrentjev Ave., Novosibirsk 630090, Russia, http://www.nioch.nsc.ru/eng/labs/mcg_e.htm.
Vladimir G VasilievVorozhtsov Novosibirsk Institute of Organic Chemistry, 9 Acad. M.A. Lavrentjev Ave., Novosibirsk 630090, Russia, http://www.nioch.nsc.ru/eng/labs/mcg_e.htm.
Leonid A ShundrinVorozhtsov Novosibirsk Institute of Organic Chemistry, 9 Acad. M.A. Lavrentjev Ave., Novosibirsk 630090, Russia, http://www.nioch.nsc.ru/eng/labs/mcg_e.htm.
Howard J HalpernThe Center for EPR Imaging in vivo Physiology, Department of Radiation and Cellular Oncology, The University of Chicago, Chicago, IL 60637, USA, http://epri.uchicago.edu/

Funding

Very Low Frequency EPR Imaging in Vivo Phisiology P41 EB02034P41EB002034 · NIBIB · UNIVERSITY OF CHICAGO · PI HALPERN, HOWARD J · 2003 to 2017
$16.1M
Radiation Biology of EPR Oxygen ImagesR01CA098575 · NCI · UNIVERSITY OF CHICAGO · PI HALPERN, HOWARD J · 2003 to 2022
$4.5M
NCI NIH HHS R01 CA098575NIBIB NIH HHS P41 EB002034
6 · The paper itself

Abstract

C-, N-, P-, and S-nucleophiles reacted with symmetrical tris(2,3,5,6-tetrathiaaryl)methyl cations, generated from the corresponding triarylmethanols by strong acids, to give a variety of asymmetrical monosubstituted persistent triaryl-methyl (TAM) radicals as the major products. The only byproducts were symmetrical TAMs.

Indexed as

CarbocationsElectron transferNucleophilic additionRadicalsReaction mechanisms

Identifiers

PMID24883040
PMCPMC4038673

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.