Evidence map›Paper›PMID 24882870›Full record

ArticleAIChE journal. American Institute of Chemical Engineers2014

Influence of the Phase State of Self-Assembling Redox Mediators on their Electrochemical Activity.

John P E Muller, Burcu S Aytar, Yukishige Kondo, David M Lynn, Nicholas L Abbott

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in AIChE journal. American Institute of Chemical Engineers, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

John P E MullerDepartment of Chemical and Biological Engineering, University of Wisconsin-Madison, 1415 Engineering Drive, Madison WI, 53706-1607, United States.
Burcu S AytarDepartment of Chemical and Biological Engineering, University of Wisconsin-Madison, 1415 Engineering Drive, Madison WI, 53706-1607, United States.
Yukishige KondoDepartment of Industrial Chemistry, Tokyo University of Science, Tokyo, Japan.
David M LynnDepartment of Chemical and Biological Engineering, University of Wisconsin-Madison, 1415 Engineering Drive, Madison WI, 53706-1607, United States.
Nicholas L AbbottDepartment of Chemical and Biological Engineering, University of Wisconsin-Madison, 1415 Engineering Drive, Madison WI, 53706-1607, United States.

Funding

BIOMOLECULAR ANALYSIS USING LIQUID CRYSTALSR01CA108467 · NCI · UNIVERSITY OF WISCONSIN-MADISON · PI ABBOTT, NICHOLAS L · 2004 to 2013
$3.8M
Rapid Analytics for Endotoxin using Liquid Crystalline DropletsR21AI092004 · NIAID · UNIVERSITY OF WISCONSIN-MADISON · PI ABBOTT, NICHOLAS L · 2011 to 2012
$401k
Spatial and Temporal Control of Transfection Using Ferrocene-Containing LipidsR21EB006168 · NIBIB · UNIVERSITY OF WISCONSIN-MADISON · PI LYNN, DAVID M · 2007 to 2008
$387k
NCI NIH HHS R01 CA108467NIAID NIH HHS R21 AI092004NIBIB NIH HHS R21 EB006168
6 · The paper itself

Abstract

Self-assembling redox mediators have the potential to be broadly useful in a range of interfacial electrochemical contexts because the oxidation state and state of assembly of the mediator are closely coupled. In this paper, we report an investigation of the self-assembly of single- and double-tailed ferrocenyl amphiphiles (FTMA and BFDMA, respectively) at the surfaces of Pt electrodes and the impact of the dynamic assembled state of the amphiphiles on their rate of oxidation. We conclude that frozen aggregates of BFDMA adsorb to the surfaces of the Pt electrodes, and that slow dynamics of reorganization BFDMA within these aggregates limits the rate of electrooxidation of BFDMA. In contrast, FTMA, while forming assemblies on the surfaces of Pt electrodes, is characterized by fast reorganization dynamics and a corresponding rate of oxidation that is an order of magnitude greater than BFDMA.

Identifiers

PMID24882870
PMCPMC4036740

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.