ArticleThe Journal of chemical physics2014
On the collective network of ionic liquid/water mixtures. IV. Kinetic and rotational depolarization.
Article in The Journal of chemical physics, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Tuning Water Networks via Ionic Liquid/Water Mixtures.International journal of molecular sciences · 2020Article
- Computational solvation analysis of biomolecules in aqueous ionic liquid mixtures : From large flexible proteins to small rigid drugs.Biophysical reviews · 2018Review
- Proteins in Ionic Liquids: Current Status of Experiments and Simulations.Topics in current chemistry (Cham) · 2017Review
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6 authors.
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Abstract
Dielectric spectroscopy is a measure of the collective Coulomb interaction in liquid systems. Adding ionic liquids to an aqueous solution results in a decrease of the static value of the generalized dielectric constant which cannot be attributed to kinetic depolarization models characterized by the static conductivity and rotational relaxation constant. However, a dipolar Poisson-Boltzmann model computing the water depolarization in the proximity of ions is not only successful for simple electrolytes but also in case of molecular ionic liquids. Moreover, our simple geometric hydration model is also capable to explain the dielectric depolarization. Both models compute the dielectric constant of water and obtain the overall dielectric constant by averaging the values of its components, water and the ionic liquid, weighted by their volume occupancies. In this sense, aqueous ionic liquid mixtures seem to behave like polar mixtures.
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