ArticleScientific reports2014
Strong non-classical induction forces in ion-surface interactions: general origin of Hofmeister effects.
Article in Scientific reports, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
4 citing papers in PubMed.
- Specific ion effects of incomplete ion-exchange by electric field-induced ion polarization.RSC advances · 2020Article
- Impact of electroviscous effect on viscosity in developing highly concentrated protein formulations: Lessons from non-protein charged colloids.International journal of pharmaceutics: X · 2019Review
- Quantitative characterization of non-classic polarization of cations on clay aggregate stability.PloS one · 2015Article
- Origin of Hofmeister Effects for Complex Systems.PloS one · 2015Article
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Authors and funding
6 authors.
Funding
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Abstract
Hofmeister effects continue to defy all-encompassing theories, and their origin is still a matter of debate. We observed strong Hofmeister effects in Ca2+/Na+ exchange on a permanently charged surface over a wide range of ionic strengths. They could not be attributed to dispersion forces, classical induction forces, ionic size, or hydration effects. We demonstrated that another stronger force was active in the ion-surface interactions, and which would create Hofmeister effects in general. The strength of this force was up to 10(4) times that of the classical induction force, and could be comparable to the Coulomb force. Coulomb, dispersion and hydration effects appeared to be interwined to affect the force. The presence of the observed strong non-classical induction force implied that energies of non-valence electrons of ions/atoms at the interface might be heavily underestimated in current theories, and possibly just those underestimated energies of non-valence electrons determined Hofmeister effects.
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Registered trials
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