Evidence map›Paper›PMID 24854224›Full record

ArticleScientific reports2014

Strong non-classical induction forces in ion-surface interactions: general origin of Hofmeister effects.

Xinmin Liu, Hang Li, Rui Li, Deti Xie, Jiupai Ni, Laosheng Wu

Abstract read
In one paragraph

Article in Scientific reports, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Xinmin LiuChongqing key laboratory of soil multi-scale interfacial process, College of Resources and Environment, Southwest University, Chongqing 400715, CHINA.
Hang LiChongqing key laboratory of soil multi-scale interfacial process, College of Resources and Environment, Southwest University, Chongqing 400715, CHINA.
Rui LiChongqing key laboratory of soil multi-scale interfacial process, College of Resources and Environment, Southwest University, Chongqing 400715, CHINA.
Deti XieChongqing key laboratory of soil multi-scale interfacial process, College of Resources and Environment, Southwest University, Chongqing 400715, CHINA.
Jiupai NiChongqing key laboratory of soil multi-scale interfacial process, College of Resources and Environment, Southwest University, Chongqing 400715, CHINA.
Laosheng WuDepartment of Environmental Sciences, University of California, Riverside, CA 92501, USA.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Hofmeister effects continue to defy all-encompassing theories, and their origin is still a matter of debate. We observed strong Hofmeister effects in Ca2+/Na+ exchange on a permanently charged surface over a wide range of ionic strengths. They could not be attributed to dispersion forces, classical induction forces, ionic size, or hydration effects. We demonstrated that another stronger force was active in the ion-surface interactions, and which would create Hofmeister effects in general. The strength of this force was up to 10(4) times that of the classical induction force, and could be comparable to the Coulomb force. Coulomb, dispersion and hydration effects appeared to be interwined to affect the force. The presence of the observed strong non-classical induction force implied that energies of non-valence electrons of ions/atoms at the interface might be heavily underestimated in current theories, and possibly just those underestimated energies of non-valence electrons determined Hofmeister effects.

Identifiers

PMID24854224
PMCPMC7365329

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.