ArticleJournal of the American Chemical Society2014
Hydroxo-bridged dicopper(II,III) and -(III,III) complexes: models for putative intermediates in oxidation catalysis.
Article in Journal of the American Chemical Society, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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Who cites it
18 citing papers in PubMed.
- Article
- The development of bioinspired copper complexes for COJournal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry · 2026Article
- Perylene Diimide-Derived Bis(Macrocyclic) Ligand Affords Chiral Multinuclear Pd(II) Complexes via Direct Bay-Region Palladation.Angewandte Chemie (International ed. in English) · 2026Article
- Three Distinct Oxidation States (II/II, II/III, and III/III) of Diorganocopper Complexes.JACS Au · 2024Article
- Dioxygenase Chemistry in Nucleophilic Aldehyde Deformylations Utilizing Dicopper OJournal of the American Chemical Society · 2024Article
- Copper-oxygen adducts: new trends in characterization and properties towards C-H activation.Chemical science · 2024Review
- Understanding C-H activation in light alkanes over Cu-MOR zeolites by coupling advanced spectroscopy and temperature-programmed reduction experiments.Chemical science · 2023Article
- Unusual Water Oxidation Mechanism via a Redox-Active Copper Polypyridyl Complex.Inorganic chemistry · 2023Article
- Spectroscopic Characterization of a Reactive [CuAngewandte Chemie (International ed. in English) · 2021Article
- A chromophore-supported structural and functional model of dinuclear copper enzymes, for facilitating mechanism of action studies.Chemical science · 2021Article
- Pyridyldiimine macrocyclic ligands: Influences of template ion, linker length and imine substitution on ligand synthesis, structure and redox properties.Polyhedron · 2021Article
- Low Reorganization Energy for Electron Self-Exchange by a Formally Copper(III,II) Redox Couple.Inorganic chemistry · 2019Article
- Ligand-Based Control of Single-Site vs. Multi-Site Reactivity by a Trichromium Cluster.Angewandte Chemie (International ed. in English) · 2019Article
- Copper Complexes of Multidentate Carboxamide Ligands.Inorganica chimica acta · 2019Article
- Copper-Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity.Chemical reviews · 2017Review
- Secondary Sphere Hydrogen Bonding in Monocopper Complexes of Potentially Dinucleating Bis(carboxamide) Ligands.European journal of inorganic chemistry · 2015Article
- Characterization and reactivity of a terminal nickel(III)-oxygen adduct.Chemistry (Weinheim an der Bergstrasse, Germany) · 2015Article
- Identification of the valence and coordination environment of the particulate methane monooxygenase copper centers by advanced EPR characterization.Journal of the American Chemical Society · 2014Article
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8 authors.
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Abstract
A macrocyclic ligand (L(4-)) comprising two pyridine(dicarboxamide) donors was used to target reactive copper species relevant to proposed intermediates in catalytic hydrocarbon oxidations by particulate methane monooxygenase and heterogeneous zeolite systems. Treatment of LH4 with base and Cu(OAc)2·H2O yielded (Me4N)2[L2Cu4(μ4-O)] (1) or (Me4N)[LCu2(μ-OH)] (2), depending on conditions. Complex 2 was found to undergo two reversible 1-electron oxidations via cyclic voltammetry and low-temperature chemical reactions. On the basis of spectroscopy and theory, the oxidation products were identified as novel hydroxo-bridged mixed-valent Cu(II)Cu(III) and symmetric Cu(III)2 species, respectively, that provide the first precedence for such moieties as oxidation catalysis intermediates.
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