ArticleThe Journal of organic chemistry2014
Cross-electrophile coupling: principles of reactivity and selectivity.
Article in The Journal of organic chemistry, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 160 papers.
What it found
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Who cites it
160 citing papers in PubMed.
- Enantioconvergent access to 1,1-diarylmethine silanes and germanes through nickel/photoredox-catalyzed cross-electrophile coupling.Chemical science · 2026Article
- Nickel-Catalyzed Cross-Electrophile Coupling of Alkynyl Halides With Allylic Acetates.Angewandte Chemie (International ed. in English) · 2026Article
- Development of Kilogram-Scale Electrochemical Ni-Catalyzed Cross Electrophile Coupling in Flow.Organic process research & development · 2026Article
- Ligand-controlled sequential activation enables nickel-catalysed alkyl-alkynyl coupling.Nature communications · 2026Article
- Metal-Catalyzed Reductive Coupling of Aryl Halides beyond Premetalated Reagents or Metallic Reductants: Biaryl Formation.Chemical reviews · 2026Review
- Ring-opening decarbonylative C(spChemical science · 2026Article
- Nickel-Catalyzed Aryl Group Interconversion: A Non-Equilibrium Strategy for Aryl Nitrile Synthesis.JACS Au · 2026Article
- Article
- Decoding the Nested, Multicycle Mechanism of Ni-Catalyzed Redox-Neutral Cross-Coupling through Temperature Scanning Reaction Calorimetry.Journal of the American Chemical Society · 2026Article
- Transition-metal-free electrochemical cross-electrophile coupling of activated benzyl alcohols and primary alkyl bromides.Science advances · 2026Article
- Enantioselective homocoupling of allenylic alcohols through divergent cooperative catalysis.Chemical science · 2025Article
- Article
- Cobalt-catalyzed reductive cross-coupling: a review.Molecular diversity · 2025Review
- 2-Substituted vs 2,9-Disubstituted Phenanthroline-NiInorganic chemistry · 2025Article
- Combining biocatalytic and radical retrosynthesis for efficient chemoenzymatic synthesis of natural products.Chemical Society reviews · 2025Review
- Asymmetric synthesis of β-amino acid derivatives by stereocontrolled C(spNature communications · 2025Article
- Synthesis of diverse terpenoid frameworks via enzyme-enabled abiotic scaffold hop.Nature chemistry · 2025Article
- Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction of Aliphatic Alcohol Derivatives.Angewandte Chemie (International ed. in English) · 2025Article
- Copper-Photoredox-Catalyzed C(spAngewandte Chemie (International ed. in English) · 2025Article
- Development of a Diastereoselective CspOrganic letters · 2025Article
100 more citing papers are in PubMed but not listed here.
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
A critical overview of the catalytic joining of two different electrophiles, cross-electrophile coupling (XEC), is presented with an emphasis on the central challenge of cross-selectivity. Recent synthetic advances and mechanistic studies have shed light on four possible methods for overcoming this challenge: (1) employing an excess of one reagent; (2) electronic differentiation of starting materials; (3) catalyst-substrate steric matching; and (4) radical chain processes. Each method is described using examples from the recent literature.
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Registered trials
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