ArticleJournal of polymer science. Part A, Polymer chemistry2013
Branched Polyphosphazenes with Controlled Dimensions.
Article in Journal of polymer science. Part A, Polymer chemistry, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- Advanced Macromolecular Architectures via Inorganic Polymers.Macromolecular rapid communications · 2026Review
- Polyphosphazene-Based Nanotherapeutics.Journal of functional biomaterials · 2025Review
- Designing polyphosphazene derivatives for gene delivery in glioblastoma treatment.Materials today. Bio · 2025Article
- Degradable Bottlebrush Polypeptides and the Impact of their Architecture on Cell Uptake, Pharmacokinetics, and Biodistribution In Vivo.Small (Weinheim an der Bergstrasse, Germany) · 2023Article
- Hybrid Porous Microparticles Based on a Single Organosilica Cyclophosphazene Precursor.International journal of molecular sciences · 2020Article
- Main-Chain Phosphorus-Containing Polymers for Therapeutic Applications.Molecules (Basel, Switzerland) · 2020Review
- DNA insecticide developed from the Lymantria dispar 5.8S ribosomal RNA gene provides a novel biotechnology for plant protection.Scientific reports · 2019Article
- Degradable, Dendritic Polyols on a Branched Polyphosphazene Backbone.Industrial & engineering chemistry research · 2018Article
- Biodegradable Polyphosphazene-Based Blends for Regenerative Engineering.Regenerative engineering and translational medicine · 2017Article
- Preparation of polyphosphazenes: a tutorial review.Chemical Society reviews · 2016Article
- Macromolecular Pt(IV) Prodrugs from Poly(organo)phosphazenes.Macromolecular bioscience · 2016Article
- Polyphosphazene Based Star-Branched and Dendritic Molecular Brushes.Macromolecular rapid communications · 2016Article
- Biodegradable Polyphosphazene Based Peptide-Polymer Hybrids.Polymers · 2016Article
- Thermoresponsive Polyphosphazene-Based Molecular Brushes by Living Cationic Polymerization.Macromolecular symposia · 2014Article
- Water-Soluble, Biocompatible Polyphosphazenes with Controllable and pH-Promoted Degradation Behavior.Journal of polymer science. Part A, Polymer chemistry · 2014Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
Using living cationic polymerization, a series of polyphosphazenes is prepared with precisely controlled molecular weights and narrow polydispersities. As well as varying chain length through the use of a living polymerization, amine-capped polyalkylene oxide (Jeffamine) side chains with varied lengths are grafted to the polymer backbone to give a series of polymers with varied dimensions. Dynamic light scattering and size exclusion chromatography are used to confirm the preparation of polymers with a variety of controlled dimensions and thus hydrodynamic volumes. Furthermore, it is demonstrated how the number of arms per repeat unit, and thus the density of branching, can also be further increased from two to four through using a one-pot thiolactone conversion of the Jeffamines, followed by thiol-yne addition to the polyphosphazene backbone. These densely branched, molecular brush-type polymers on a biodegradable polyphosphazene backbone all show excellent aqueous solubility and have potential in drug-delivery applications.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.