Evidence map›Paper›PMID 24705907›Full record

ArticleDalton transactions (Cambridge, England : 2003)2014

Thioether-ligated iron(II) and iron(III)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere.

Leland R Widger, Yunbo Jiang, Alison C McQuilken, Tzuhsiung Yang, Maxime A Siegler, Hirotoshi Matsumura, Pierre Moënne-Loccoz, Devesh Kumar, Sam P de Visser, David P Goldberg

Abstract read
In one paragraph

Article in Dalton transactions (Cambridge, England : 2003), 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.

0numbers the graph read from it
0cells of the map it votes in
9citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

9 citing papers in PubMed.

  1. Article
  2. Article
  3. Investigating Ligand Sphere Perturbations on MnMolecules (Basel, Switzerland) · 2024
    Article
  4. Article
  5. Article
  6. Article
  7. Mononuclear, Nonheme, High-Spin {FeNO}Inorganic chemistry · 2019
    Article
  8. A Mononuclear, Nonheme FeJournal of the American Chemical Society · 2019
    Article
  9. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Leland R WidgerDepartment of Chemistry, The Johns Hopkins University, 3400 North Charles Street, Baltimore, Maryland 21218, USA. dpg@jhu.edu.
Yunbo Jiang
Alison C McQuilken
Tzuhsiung Yang
Maxime A Siegler
Hirotoshi Matsumura
Pierre Moënne-Loccoz
Devesh Kumar
Sam P de Visser
David P Goldberg

Funding

Nitric Oxide Reactions in MetalloenzymesR01GM074785 · NIGMS · OREGON HEALTH & SCIENCE UNIVERSITY · PI MOENNE-LOCCOZ, PIERRE · 2006 to 2019
$3.8M
Reactivity of Manganese and Iron Metalloenzyme ModelsR01GM101153 · NIGMS · JOHNS HOPKINS UNIVERSITY · PI GOLDBERG, DAVID P · 2013 to 2023
$3.4M
Synthetic Models of N/S-Ligated Metal Centers in BiologyR01GM062309 · NIGMS · JOHNS HOPKINS UNIVERSITY · PI GOLDBERG, DAVID P · 2001 to 2010
$2.2M
NIGMS NIH HHS GM074785NIGMS NIH HHS GM101153NIGMS NIH HHS GM62309NIGMS NIH HHS R01 GM062309NIGMS NIH HHS R01 GM074785NIGMS NIH HHS R01 GM101153
6 · The paper itself

Abstract

The non-heme iron complexes, [Fe(II)(N3PySR)(CH3CN)](BF4)2 () and [Fe(II)(N3Py(amide)SR)](BF4)2 (), afford rare examples of metastable Fe(iii)-OOH and Fe(iii)-OOtBu complexes containing equatorial thioether ligands and a single H-bond donor in the second coordination sphere. These peroxo complexes were characterized by a range of spectroscopic methods and density functional theory studies. The influence of a thioether ligand and of one H-bond donor on the stability and spectroscopic properties of these complexes was investigated.

Indexed as

Biomimetic MaterialsFerric CompoundsHydrogen BondingIronModels, MolecularMolecular ConformationSulfurFerric CompoundsIronSulfur

Identifiers

PMID24705907
PMCPMC4319814

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.