ArticleMacromolecular rapid communications2014
Chain-end-functionalized polyphosphazenes via a one-pot phosphine-mediated living polymerization.
Article in Macromolecular rapid communications, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
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Who cites it
22 citing papers in PubMed.
- Accelerated Mucopermeation and Penetration of the Polypeptide Antibiotic Colistin via Ionic Complexation with Polyphosphazene Carriers.ACS omega · 2026Article
- Concentration-Driven Reversible Morphological Transitions by the Self-Assembly of Crystalline-Coil Polyphosphazene-b-Polystyrene (PP-b-PS) Block Copolymers.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Dehydrocoupling of Phosphine-Borane Adducts Under Ambient Conditions Using Aminoboranes as Hydrogen Acceptors.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Inorganic Bottlebrush and Comb Polymers as a Platform for Supersoft, Solvent-Free Elastomers.ACS polymers Au · 2024Article
- Superfluorinated, Highly Water-Soluble Polyphosphazenes as PotentialJournal of functional biomaterials · 2024Article
- Degradable Bottlebrush Polypeptides and the Impact of their Architecture on Cell Uptake, Pharmacokinetics, and Biodistribution In Vivo.Small (Weinheim an der Bergstrasse, Germany) · 2023Article
- Phosphorus-Containing Polymers as Sensitive Biocompatible Probes forMolecules (Basel, Switzerland) · 2023Article
- Phosphazene Cyclomatrix Network-Based Polymer: Chemistry, Synthesis, and Applications.ACS omega · 2022Review
- Hollow Silica Microparticles Based on Amphiphilic Polyphosphazenes.Materials (Basel, Switzerland) · 2022Article
- Hetero and homo α,ω-chain-end functionalized polyphosphazenes.Journal of polymer science (2020) · 2022Article
- Polyphosphazene-Based Nanocarriers for the Release of Camptothecin and Epirubicin.Pharmaceutics · 2022Article
- Reversible Speed Regulation of Self-Propelled Janus Micromotors via Thermoresponsive Bottle-Brush Polymers.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Controlled Synthesis of Polyphosphazenes with Chain-Capping Agents.Molecules (Basel, Switzerland) · 2021Article
- Dual stimuli-responsive polyphosphazene-based molecular gates for controlled drug delivery in lung cancer cells.RSC advances · 2020Article
- Main-Chain Phosphorus-Containing Polymers for Therapeutic Applications.Molecules (Basel, Switzerland) · 2020Review
- Cylindrical Micelles by the Self-Assembly of Crystalline-Molecules (Basel, Switzerland) · 2019Article
- Stimuli-Responsive Phosphorus-Based Polymers.European journal of inorganic chemistry · 2019Review
- Oxidation Responsive Polymers with a Triggered Degradation via Arylboronate Self-Immolative Motifs on a Polyphosphazene Backbone.ACS macro letters · 2017Article
- Preparation of polyphosphazenes: a tutorial review.Chemical Society reviews · 2016Article
- Polyphosphazene Based Star-Branched and Dendritic Molecular Brushes.Macromolecular rapid communications · 2016Article
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Authors and funding
5 authors.
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Abstract
A simple polymerization of trichlorophosphoranimine (Cl3 P = N-SiMe3 ) mediated by functionalized triphenylphosphines is presented. In situ initiator formation and the subsequent polymerization progress are investigated by (31) P NMR spectroscopy, demonstrating a living cationic polymerization mechanism. The polymer chain lengths and molecular weights of the resulting substituted poly(organo)phosphazenes are further studied by (1) H NMR spectroscopy and size exclusion chromatography. This strategy facilitates the preparation of polyphosphazenes with controlled molecular weights and specific functional groups at the α-chain end. Such well-defined, mono-end-functionalized polymers have great potential use in bioconjugation, surface modification, and as building blocks for complex macromolecular constructs.
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