ArticleJournal of the American Chemical Society2014
Dynamic nuclear polarization NMR enables the analysis of Sn-Beta zeolite prepared with natural abundance ¹¹⁹Sn precursors.
Article in Journal of the American Chemical Society, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed.
- Mechanistic Insights into Nitroarene Hydrogenation Dynamics on Pt(111) viaJournal of the American Chemical Society · 2025Article
- Adsorbate-driven dynamic active sites in stannosilicate zeolites.Fundamental research · 2025Article
- Structural characterization of tin in toothpaste by dynamic nuclear polarization enhancedNature communications · 2023Article
- Tracking Lattice Distortion Induced by Defects and Framework Tin in Beta Zeotypes.The journal of physical chemistry. C, Nanomaterials and interfaces · 2023Article
- Emerging analytical methods to characterize zeolite-based materials.National science review · 2022Review
- Recent advances in solid-state NMR of zeolite catalysts.National science review · 2022Review
- Surface enhanced dynamic nuclear polarization solid-state NMR spectroscopy sheds light on Brønsted-Lewis acid synergy during the zeolite catalyzed methanol-to-hydrocarbon process.Chemical science · 2019Article
- Fast detection and structural identification of carbocations on zeolites by dynamic nuclear polarization enhanced solid-state NMR.Chemical science · 2018Article
- Predicting the DNP-SENS efficiency in reactive heterogeneous catalysts from hydrophilicity.Chemical science · 2018Article
- Engineering of Transition Metal Catalysts Confined in Zeolites.Chemistry of materials : a publication of the American Chemical Society · 2018Review
- Continuous wave electron paramagnetic resonance of nitroxide biradicals in fluid solution.Concepts in magnetic resonance. Part A, Bridging education and research · 2018Article
- Porous metallosilicates for heterogeneous, liquid-phase catalysis: perspectives and pertaining challenges.Royal Society open science · 2018Review
- Efficient assignment and NMR analysis of an intact virus using sequential side-chain correlations and DNP sensitization.Proceedings of the National Academy of Sciences of the United States of America · 2017Article
- Donor-acceptor stacking arrangements in bulk and thin-film high-mobility conjugated polymers characterized using molecular modelling and MAS and surface-enhanced solid-state NMR spectroscopy.Chemical science · 2017Article
- Dendritic polarizing agents for DNP SENS.Chemical science · 2017Article
- Interrogating the Lewis Acidity of Metal Sites in Beta Zeolites withThe journal of physical chemistry. C, Nanomaterials and interfaces · 2016Article
- Dynamic nuclear polarization at 40 kHz magic angle spinning.Physical chemistry chemical physics : PCCP · 2016Article
- Atomic Description of the Interface between Silica and Alumina in Aluminosilicates through Dynamic Nuclear Polarization Surface-Enhanced NMR Spectroscopy and First-Principles Calculations.Journal of the American Chemical Society · 2015Article
- Formation of Organic Molecular Nanocrystals under Rigid Confinement with Analysis by Solid State NMR.CrystEngComm · 2014Article
- Dynamic nuclear polarization of (1)H, (13)C, and (59)Co in a tris(ethylenediamine)cobalt(III) crystalline lattice doped with Cr(III).Journal of the American Chemical Society · 2014Article
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5 authors.
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Abstract
The catalytic activity of tin-containing zeolites, such as Sn-Beta, is critically dependent on the successful incorporation of the tin metal center into the zeolite framework. However, synchrotron-based techniques or solid-state nuclear magnetic resonance (ssNMR) of samples enriched with (119)Sn isotopes are the only reliable methods to verify framework incorporation. This work demonstrates, for the first time, the use of dynamic nuclear polarization (DNP) NMR for characterizing zeolites containing ~2 wt % of natural abundance Sn without the need for (119)Sn isotopic enrichment. The biradicals TOTAPOL, bTbK, bCTbK, and SPIROPOL functioned effectively as polarizing sources, and the solvent enabled proper transfer of spin polarization from the radical's unpaired electrons to the target nuclei. Using bCTbK led to an enhancement (ε) of 75, allowing the characterization of natural-abundance (119)Sn-Beta with excellent signal-to-noise ratios in <24 h. Without DNP, no (119)Sn resonances were detected after 10 days of continuous analysis.
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