ArticleAngewandte Chemie (International ed. in English)2014
Gold(I) as an artificial cyclase: short stereodivergent syntheses of (-)-epiglobulol and (-)-4β,7α- and (-)-4α,7α-aromadendranediols.
Article in Angewandte Chemie (International ed. in English), 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- Marine Natural Products From Indonesia and Their Biosynthetic Origins: Part 1: Terpenoids and Meroterpenoids.Chemistry & biodiversity · 2026Review
- Gold-Catalyzed Synthesis of Small Rings.Chemical reviews · 2021Article
- An invocation for computational evaluation of isomerization transforms: cationic skeletal reorganizations as a case study.Natural product reports · 2021Review
- Assembly of Complex 1,4-Cycloheptadienes by (4+3) Cycloaddition of Rhodium(II) and Gold(I) Non-Acceptor Carbenes.Angewandte Chemie (International ed. in English) · 2021Article
- Shapeshifting molecules: the story so far and the shape of things to come.Chemical science · 2020Review
- Recent Advances in Construction of Polycyclic Natural Product Scaffolds via One-Pot Reactions Involving Alkyne Annulation.Frontiers in chemistry · 2020Review
- Ionization of gold (γ-methoxy)vinyl complexes generates reactive gold vinyl carbene complexes.Chemical science · 2019Article
- StereoselectiveACS catalysis · 2017Article
- Ready Access to the Echinopines Skeleton via Gold(I)-Catalyzed Alkoxycyclizations of Enynes.The Journal of organic chemistry · 2016Article
- α,β-Unsaturated Gold(I) Carbenes by Tandem Cyclization and 1,5-Alkoxy Migration of 1,6-Enynes: Mechanisms and Applications.Chemistry (Weinheim an der Bergstrasse, Germany) · 2016Article
- Synthesis of Rumphellaone A and Hushinone by a Gold-Catalyzed [2 + 2] Cycloaddition.Organic letters · 2016Article
- Gold(I)-Catalyzed Inter- and Intramolecular Additions of Carbonyl Compounds to Allenenes.Organic letters · 2016Article
- Cooperative benzylic-oxyallylic stabilized cations: regioselective construction of α-quaternary centers in ketone-derived compounds.Chemical science · 2015Article
- Gold(I)-Catalyzed Activation of Alkynes for the Construction of Molecular Complexity.Chemical reviews · 2015Article
- Gold-Catalyzed Reactions via Cyclopropyl Gold Carbene-like Intermediates.The Journal of organic chemistry · 2015Article
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4 authors.
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No grant is acknowledged in the PubMed record.
Abstract
Three natural aromadendrane sesquiterpenes, (-)-epiglobulol, (-)-4β,7α-aromadendranediol, and (-)-4α,7α-aromadendranediol, have been synthesized in only seven steps in 12, 15, and 17 % overall yields, respectively, from (E,E)-farnesol by a stereodivergent gold(I)-catalyzed cascade reaction which forms the tricyclic aromadendrane core in a single step. These are the shortest total syntheses of these natural compounds.
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