ArticleAngewandte Chemie (International ed. in English)2014
Application of fundamental organometallic chemistry to the development of a gold-catalyzed synthesis of sulfinate derivatives.
Article in Angewandte Chemie (International ed. in English), 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 23 papers.
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Who cites it
23 citing papers in PubMed.
- Asymmetric Desymmetrizing Sulfonylation of Diarylmethanes via Peptidyl-Cu(I)-Catalysis with Remote Stereocontrol.Journal of the American Chemical Society · 2026Article
- Copper acetate mediated thiomethylation of 2-pyridine-substituted acrylonitriles with DMSO.RSC advances · 2025Article
- Palladium-Catalyzed Tsuji-Trost-Type Reaction of 3-Indolylmethylacetates with O, and S Soft Nucleophiles.Molecules (Basel, Switzerland) · 2024Article
- Metal-free synthesis of γ-ketosulfones through Brønsted acid-promoted conjugate addition of sulfinamides.RSC advances · 2024Article
- An efficient and mild oxidative approach from thiols to sulfonyl derivatives with DMSO/HBr.Chemical science · 2023Article
- Photocatalytic conversion of aryl diazonium salts to sulfonyl fluorides.Tetrahedron · 2023Article
- Migratory Insertion of CO into a Au-C Bond.Journal of the American Chemical Society · 2022Article
- Scalable, Chemoselective Nickel Electrocatalytic Sulfinylation of Aryl Halides with SOAngewandte Chemie (International ed. in English) · 2022Article
- Tricomponent Decarboxysulfonylative Cross-Coupling Facilitates Direct Construction of Aryl Sulfones and Reveals a Mechanistic Dualism in the Acridine/Copper Photocatalytic System.ACS catalysis · 2022Article
- Functional group divergence and the structural basis of acridine photocatalysis revealed by direct decarboxysulfonylation.Chemical science · 2022Article
- Redox-Neutral Organometallic Elementary Steps at Bismuth: Catalytic Synthesis of Aryl Sulfonyl Fluorides.Journal of the American Chemical Society · 2021Article
- Palladium-catalyzed Tsuji-Trost-type reaction of benzofuran-2-ylmethyl acetates with nucleophiles.RSC advances · 2020Article
- A combined spectroscopic andRSC advances · 2020Article
- An efficient approach for the synthesis of novel methyl sulfones in acetic acid medium and evaluation of antimicrobial activity.Turkish journal of chemistry · 2020Article
- Bond-Forming and -Breaking Reactions at Sulfur(IV): Sulfoxides, Sulfonium Salts, Sulfur Ylides, and Sulfinate Salts.Chemical reviews · 2019Article
- Cross-Coupling of Sodium Sulfinates with Aryl, Heteroaryl, and Vinyl Halides by Nickel/Photoredox Dual Catalysis.Angewandte Chemie (International ed. in English) · 2018Article
- Migratory Insertion of Carbenes into Au(III)-C Bonds.Journal of the American Chemical Society · 2018Article
- Copper(i)-catalyzed sulfonylative Suzuki-Miyaura cross-coupling.Chemical science · 2017Article
- One-pot palladium-catalyzed synthesis of sulfonyl fluorides from aryl bromides.Chemical science · 2017Article
- Palladium(II)-Catalyzed Synthesis of Sulfinates from Boronic Acids and DABSO: A Redox-Neutral, Phosphine-Free Transformation.Angewandte Chemie (International ed. in English) · 2016Article
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Authors and funding
6 authors.
Funding
Abstract
The development of a gold(I)-catalyzed sulfination of aryl boronic acids is described. This transformation proceeds through an unprecedented mechanism which exploits the reactivity of gold(I)-heteroatom bonds to form sulfinate anions. Further in situ elaboration of the sulfinate intermediates leads to the corresponding sulfones and sulfonamides, two pharmacophores routinely encountered in drug discovery.
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