ArticleNature materials2014
Microimaging of transient guest profiles to monitor mass transfer in nanoporous materials.
Article in Nature materials, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 36 papers.
What it found
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Who cites it
36 citing papers in PubMed.
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- Visualizing Composition and Functionality of Porous Catalysts Using Dual-Emissive Fluorescent Nanoprobes.ACS central science · 2025Article
- Asymmetric rotations slow down diffusion under confinement.Nature communications · 2025Article
- Reply to: Diffusion anomaly in nanopores as a rich field for theorists and a challenge for experimentalists.Nature communications · 2024Article
- Diffusion anomaly in nanopores as a rich field for theorists and a challenge for experimentalists.Nature communications · 2024Article
- Precise control over gas-transporting channels in zeolitic imidazolate framework glasses.Nature materials · 2024Article
- Molecular Catalysis of Energy Relevance in Metal-Organic Frameworks: From Higher Coordination Sphere to System Effects.Chemical reviews · 2023Review
- Hyperloop-like diffusion of long-chain molecules under confinement.Nature communications · 2023Article
- Hydrocarbon Sorption in Flexible MOFs-Part II: Understanding Adsorption Kinetics.Nanomaterials (Basel, Switzerland) · 2023Article
- Zeolites in Adsorption Processes: State of the Art and Future Prospects.Chemical reviews · 2022Review
- Multiscale dynamical cross-talk in zeolite-catalyzed methanol and dimethyl ether conversions.National science review · 2022Article
- Molecular insight into the diffusion/flow potential properties initiated by methane adsorption in coal matrix: taking the factor of moisture contents into account.Environmental science and pollution research international · 2022Article
- Unravelling Channel Structure-Diffusivity Relationships in Zeolite ZSM-5 at the Single-Molecule Level.Angewandte Chemie (International ed. in English) · 2022Article
- Electrochemical Modification on CHACS omega · 2021Article
- Effect of External Surface Diffusion Barriers on Platinum/Beta-Catalyzed Isomerization of n-Pentane.Angewandte Chemie (International ed. in English) · 2021Article
- Chemical Imaging of Hierarchical Porosity Formation within a Zeolite Crystal Visualized by Small-Angle X-Ray Scattering and In-Situ Fluorescence Microscopy.Angewandte Chemie (International ed. in English) · 2021Article
- Diffusion and catalyst efficiency in hierarchical zeolite catalysts.National science review · 2020Article
- Imaging spatiotemporal evolution of molecules and active sites in zeolite catalyst during methanol-to-olefins reaction.Nature communications · 2020Article
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The intense interactions of guest molecules with the pore walls of nanoporous materials is the subject of continued fundamental research. Stimulated by their thermal energy, the guest molecules in these materials are subject to a continuous, irregular motion, referred to as diffusion. Diffusion, which is omnipresent in nature, influences the efficacy of nanoporous materials in reaction and separation processes. The recently introduced techniques of microimaging by interference and infrared microscopy provide us with a wealth of information on diffusion, hitherto inaccessible from commonly used techniques. Examples include the determination of surface barriers and the sticking coefficient's analogue, namely the probability that, on colliding with the particle surface, a molecule may continue its diffusion path into the interior. Microimaging is further seen to open new vistas in multicomponent guest diffusion (including the detection of a reversal in the preferred diffusion pathways), in guest-induced phase transitions in nanoporous materials and in matching the results of diffusion studies under equilibrium and non-equilibrium conditions.
Identifiers
24651427What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.