ArticleJournal of the American Chemical Society2014
Ligand-controlled asymmetric arylation of aliphatic α-amino anion equivalents.
Article in Journal of the American Chemical Society, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 30 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
30 citing papers in PubMed, 115 citations in OpenAlex.
- Stereospecific Epoxide-to-Cyclopropylamine Conversion by a Homologous Horner-Wadsworth-Emmons-Type Reaction With an Imine-Substituted Phosphine Oxide.Angewandte Chemie (International ed. in English) · 2026Article
- Integrating Catalysis and Analysis: Accelerated Asymmetric Reaction Development With a Multitasking Reactivity Umpolung/Chiroptical Reporter Auxiliary.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Synergistic Pd/Cu-catalyzed enantioselective CspNature communications · 2022Article
- α-Branched amines through radical coupling with 2-azaallyl anions, redox active esters and alkenes.Chemical science · 2022Article
- Transition-metal-free allylation of 2-azaallyls with allyl ethers through polar and radical mechanisms.Nature communications · 2021Article
- Nickel-catalyzed enantioselective vinylation of aryl 2-azaallyl anions.Chemical science · 2021Article
- Catalytic asymmetric synthesis of quaternary trifluoromethyl α- to ε-amino acid derivativesChemical science · 2020Article
- One Amine-3 Tasks: Reductive Coupling of Imines with Olefins in Batch and Flow.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Distinctive reactivity ofBeilstein journal of organic chemistry · 2020Article
- 2-Azadienes as Enamine Umpolung Synthons for the Preparation of Chiral Amines.Synlett : accounts and rapid communications in synthetic organic chemistry · 2019Article
- Direct Catalytic Asymmetric Synthesis of Trifluoromethylated γ-Amino Esters/Lactones via Umpolung Strategy.The Journal of organic chemistry · 2019Article
- Palladium-Catalyzed Synthesis ofACS catalysis · 2019Article
- Intramolecular Umpolung Synthesis of Exocyclic β-Amino Alcohols through Decarboxylative Amination.ACS omega · 2018Article
- Control of chemoselectivity in asymmetric tandem reactions: Direct synthesis of chiral amines bearing nonadjacent stereocenters.Proceedings of the National Academy of Sciences of the United States of America · 2018Article
- Catalytic Asymmetric Synthesis of Trifluoromethylated γ-Amino Acids through the Umpolung Addition of Trifluoromethyl Imines to Carboxylic Acid Derivatives.Angewandte Chemie (International ed. in English) · 2018Article
- 2-Azadienes as Reagents for Preparing Chiral Amines: Synthesis of 1,2-Amino Tertiary Alcohols by Cu-Catalyzed Enantioselective Reductive Couplings with Ketones.Journal of the American Chemical Society · 2018Article
- Cu-Catalyzed Three-Component Carboamination of Alkenes.Journal of the American Chemical Society · 2018Article
- Transition-metal-free chemo- and regioselective vinylation of azaallyls.Nature chemistry · 2017Article
- Catalytic Asymmetric Synthesis of Chiral γ-Amino Ketones via Umpolung Reactions of Imines.Journal of the American Chemical Society · 2016Article
- Tandem C(spAdvanced synthesis & catalysis · 2016Article
Corrections and comments
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
Abstract
A palladium-catalyzed asymmetric arylation of 9-aminofluorene-derived imines using a chiral dialkylbiaryl phosphine as the supporting ligand has been developed. This transformation allows for enantioselective access to a diverse range of α-branched benzylamines.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.