ArticleNature chemistry2014
Induced-fit catalysis of corannulene bowl-to-bowl inversion.
Article in Nature chemistry, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 34 papers.
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Who cites it
34 citing papers in PubMed, 174 citations in OpenAlex.
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- Enhancing corannulene chemiluminescence, electrochemiluminescence and photoluminescence by means of an azabora-helicene to slow down its bowl inversion.Chemical science · 2024Article
- Symmetry-Constrained Properties Behave Differently for 2D or 3D Structures under the Same Point Group.The journal of physical chemistry. A · 2024Article
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- NIR-II photothermal conversion and imaging based on a cocrystal containing twisted components.Chemical science · 2024Article
- Mutual induced fit transition structure stabilization of corannulene's bowl-to-bowl inversion in a perylene bisimide cyclophane.Chemical science · 2024Article
- Room-Temperature Multiple Phosphorescence from Functionalized Corannulenes: Temperature Sensing and Afterglow Organic Light-Emitting Diode.Angewandte Chemie (International ed. in English) · 2023Article
- Catalytic effect of graphene on the inversion of corannulene using a continuum approach with the Lennard-Jones potential.Nanoscale advances · 2023Article
- Conformationally Confined Emissive Cationic Macrocycle with Photocontrolled Organelle-Specific Translocation.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Article
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- A contorted nanographene shelter.Nature communications · 2021Article
- Ion Mobility Mass Spectrometry Uncovers Guest-Induced Distortions in a Supramolecular Organometallic Metallosquare.Angewandte Chemie (International ed. in English) · 2021Article
- A curved host and second guest cooperatively inhibit the dynamic motion of corannulene.Nature communications · 2021Article
- A facile and efficient route to one-pot synthesis of new cyclophanes using vinamidinium salts.RSC advances · 2021Article
- Flat corannulene: when a transition state becomes a stable molecule.Chemical science · 2020Article
- Porphyrin-based systems containing polyaromatic fragments: decoupling the synergistic effects in aromatic-porphyrin-fullerene systems.RSC advances · 2020Article
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Authors and funding
8 authors at 2 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Stereoelectronic complementarity between the active site of an enzyme and the transition state of a reaction is one of the tenets of enzyme catalysis. This report illustrates the principles of enzyme catalysis (first proposed by Pauling and Jencks) through a well-defined model system that has been fully characterized crystallographically, computationally and kinetically. Catalysis of the bowl-to-bowl inversion processes that pertain to corannulene is achieved by combining ground-state destabilization and transition-state stabilization within the cavity of an extended tetracationic cyclophane. This synthetic receptor fulfils a role reminiscent of a catalytic antibody by stabilizing the planar transition state for the bowl-to-bowl inversion of (ethyl)corannulene (which accelerates this process by a factor of ten at room temperature) by an induced-fit mechanism first formulated by Koshland.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.