ArticleInorganic chemistry2014
Synthesis, spectroscopy, and hydrogen/deuterium exchange in high-spin iron(II) hydride complexes.
Article in Inorganic chemistry, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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16 citing papers in PubMed, 38 citations in OpenAlex.
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- Mössbauer and Nuclear Resonance Vibrational Spectroscopy Studies of Iron Species Involved in N-N Bond Cleavage.Inorganic chemistry · 2023Article
- Interplay between β-Diimino and β-Diketiminato Ligands in Nickel Complexes Active in the Proton Reduction Reaction.Inorganic chemistry · 2022Article
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- Photo-Initiated Cobalt-Catalyzed Radical Olefin Hydrogenation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Access to Metal Centers and Fluxional Hydride Coordination Integral for COInorganic chemistry · 2021Article
- Roles of Iron Complexes in Catalytic Radical Alkene Cross-Coupling: A Computational and Mechanistic Study.Journal of the American Chemical Society · 2019Article
- Carbon Dioxide Insertion into Bridging Iron Hydrides: Kinetic and Mechanistic Studies.European journal of inorganic chemistry · 2019Article
- High-Frequency Fe-H Vibrations in a Bridging Hydride Complex Characterized by NRVS and DFT.Angewandte Chemie (International ed. in English) · 2018Article
- Selective [1,4]-Hydrovinylation of 1,3-Dienes with Unactivated Olefins Enabled by Iron Diimine Catalysts.Journal of the American Chemical Society · 2018Article
- Synthesis and Mechanism of Formation of Hydride-Sulfide Complexes of Iron.Inorganic chemistry · 2017Article
- Density Functional Calculations for Prediction ofACS omega · 2017Article
- Reactivity of hydride bridges in a high-spin [FeChemical science · 2017Article
- The Mechanism of N-N Double Bond Cleavage by an Iron(II) Hydride Complex.Journal of the American Chemical Society · 2016Article
- Insight into the Iron-Molybdenum Cofactor of Nitrogenase from Synthetic Iron Complexes with Sulfur, Carbon, and Hydride Ligands.Journal of the American Chemical Society · 2016Review
- Synthesis, Characterization, and Nitrogenase-Relevant Reactions of an Iron Sulfide Complex with a Bridging Hydride.Journal of the American Chemical Society · 2015Article
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Authors and funding
5 authors at 3 institutions in 2 countries.
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Abstract
Very few hydride complexes are known in which the metals have a high-spin electronic configuration. We describe the characterization of several high-spin iron(II) hydride/deuteride isotopologues and their exchange reactions with one another and with H2/D2. Though the hydride/deuteride signal is not observable in NMR spectra, the choice of isotope has an influence on the chemical shifts of distant protons in the dimers through the paramagnetic isotope effect on chemical shift. This provides the first way to monitor the exchange of H and D in the bridging positions of these hydride complexes. The rate of exchange depends on the size of the supporting ligand, and this is consistent with the idea that H2/D2 exchange into the hydrides occurs through the dimeric complexes rather than through a transient monomer. The understanding of H/D exchange mechanisms in these high-spin iron hydride complexes may be relevant to postulated nitrogenase mechanisms.
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