Evidence map›Paper›PMID 24483247›Full record

ArticleJournal of the American Chemical Society2014

Enantioselective cycloaddition of münchnones onto [60]fullerene: organocatalysis versus metal catalysis.

Juan Marco-Martínez, Silvia Reboredo, Marta Izquierdo, Vanesa Marcos, Juan Luis López, Salvatore Filippone, Nazario Martín

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Juan Marco-MartínezDepartamento de Química Orgánica I, Facultad de Química, Universidad Complutense , E-28040 Madrid, Spain.
Silvia Reboredo
Marta Izquierdo
Vanesa Marcos
Juan Luis López
Salvatore Filippone
Nazario Martín

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Novel chiral catalytic systems based on both organic compounds and metal salts have been developed for the enantioselective [3 + 2] cycloaddition of münchnones onto fullerenes and olefins. These two different approaches proved to be efficient and complementary in the synthesis of optically active pyrrolino[3,4:1,2][60]fullerenes with high levels of enantiomeric excess and moderate to good conversions. Further functionalization of the pyrrolinofullerene carboxylic acid derivatives has been carried out by esterification and amidation reactions.

Indexed as

CatalysisCycloaddition ReactionFullerenesLigandsMaleimidesMetalsOrganic ChemicalsOxazolesOxazoloneStereoisomerismSubstrate Specificityfullerene C60FullerenesLigandsMaleimidesMetalsN-phenylmaleimideOrganic ChemicalsOxazolesOxazolone

Identifiers

PMID24483247
PMCPMC3954715

What OpenQuestion holds

Textmetadata
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.