ReviewJournal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry2014
High-frequency and high-field electron paramagnetic resonance (HFEPR): a new spectroscopic tool for bioinorganic chemistry.
Review in Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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14 citing papers in PubMed.
- Direct oxidative carbonylation of methane to acetic acid via high-valent iron-oxo mediated water activation.Nature communications · 2026Article
- Magnetospectroscopic Studies of a Series of Fe(II) Scorpionate Complexes: Assessing the Relationship between Halide Identity and Zero-Field Splitting.Inorganic chemistry · 2025Article
- Spectroscopic and Theoretical Investigation of High-Spin Square-Planar and Trigonal Fe(II) Complexes Supported by Fluorinated Alkoxides.Inorganic chemistry · 2024Article
- Formation of a Reactive [Mn(III)-O-Ce(IV)] Species and its Facile Equilibrium with Related Mn(IV)(OX) (X = Sc or H) Complexes.Angewandte Chemie (International ed. in English) · 2024Article
- Magnetic anisotropy and structural flexibility in the field-induced single ion magnets [Co{(OPPhDalton transactions (Cambridge, England : 2003) · 2023Article
- Recent advances in microresonators and supporting instrumentation for electron paramagnetic resonance spectroscopy.The Review of scientific instruments · 2022Article
- Metal-Free Biomass-Derived Environmentally Persistent Free Radicals (Bio-EPFRs) from Lignin Pyrolysis.ACS omega · 2022Article
- The Spectroscopy of Nitrogenases.Chemical reviews · 2020Review
- Nuclear-spin-pattern control of electron-spin dynamics in a series of V(iv) complexes.Chemical science · 2019Article
- Structural, Spectroscopic, Electrochemical, and Magnetic Properties for Manganese(II) Triazamacrocyclic Complexes.Inorganica chimica acta · 2019Article
- Computational investigations of click-derived 1,2,3-triazoles as keystone ligands for complexation with transition metals: a review.RSC advances · 2018Review
- Rapid and precise determination of zero-field splittings by terahertz time-domain electron paramagnetic resonance spectroscopy.Chemical science · 2017Article
- A flexible iron(ii) complex in which zero-field splitting is resistant to structural variation.Chemical science · 2016Article
- Exploring the Fe(III) binding sites of human serum transferrin with EPR at 275 GHz.Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry · 2015Article
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Abstract
This minireview describes high-frequency and high-field electron paramagnetic resonance (HFEPR) spectroscopy in the context of its application to bioinorganic chemistry, specifically to metalloproteins and model compounds. HFEPR is defined as frequencies above ~100 GHz (i.e., above W-band) and a resonant field reaching 25 T and above. The ability of HFEPR to provide high-resolution determination of g values of S = 1/2 is shown; however, the main aim of the minireview is to demonstrate how HFEPR can extract spin Hamiltonian parameters [zero-field splitting (zfs) and g values] for species with S > 1/2 with an accuracy and precision unrivalled by other physical methods. Background theory on the nature of zfs in S = 1, 3/2, 2, and 5/2 systems is presented, along with selected examples of HFEPR spectroscopy of each that are relevant to bioinorganic chemistry. The minireview also provides some suggestions of specific systems in bioinorganic chemistry where HFEPR could be rewardingly applied, in the hope of inspiring workers in this area.
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