ArticleJournal of the American Chemical Society2014
Dramatically accelerated selective oxygen-atom transfer by a nonheme iron(IV)-oxo complex: tuning of the first and second coordination spheres.
Article in Journal of the American Chemical Society, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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Who cites it
18 citing papers in PubMed, 64 citations in OpenAlex.
- Secondary-sphere hydrogen bonding promotes catalytic nitrate reduction at iron.Nature chemistry · 2026Article
- A Mononuclear Ruthenium(V)-Imido Complex With Hydrogen Bonding in the Second Coordination Sphere Forming Aziridines Without N-Substituents From Alkenes in Water.Angewandte Chemie (International ed. in English) · 2026Article
- High-Valent Late Transition Metal-Oxo Complexes: Breaking Boundaries at the Oxo Wall and Beyond.Chemical reviews · 2026Review
- Review
- Selective Metal-ion Complexation of a Biomimetic Calix[6]arene Funnel Cavity Functionalized with Phenol or Quinone.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Distinct Reactivity Modes of a Copper Hydride Enabled by an Intramolecular Lewis Acid.Journal of the American Chemical Society · 2022Article
- Di- and Tetrairon(III) μ-Oxido Complexes of an N3S-Donor Ligand: Catalyst Precursors for Alkene Oxidations.Frontiers in chemistry · 2019Article
- C-H activation and nucleophilic substitution in a photochemically generated high valent iron complex.Chemical science · 2018Article
- Mono- and binuclear non-heme iron chemistry from a theoretical perspective.Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry · 2016Review
- An iron-oxygen intermediate formed during the catalytic cycle of cysteine dioxygenase.Chemical communications (Cambridge, England) · 2016Article
- Hydrogen Bonds Dictate the Coordination Geometry of Copper: Characterization of a Square-Planar Copper(I) Complex.Angewandte Chemie (International ed. in English) · 2016Article
- Tuning the Reactivity of Mononuclear Nonheme Manganese(IV)-Oxo Complexes by Triflic Acid.Chemical science · 2015Article
- Hydrogen-bonding interactions trigger a spin-flip in iron(III) porphyrin complexes.Angewandte Chemie (International ed. in English) · 2015Article
- Hydrogen-Bonding Interactions Trigger a Spin-Flip in Iron(III) Porphyrin Complexes.Angewandte Chemie (Weinheim an der Bergstrasse, Germany) · 2015Article
- Ferryl protonation in oxoiron(IV) porphyrins and its role in oxygen transfer.Journal of the American Chemical Society · 2015Article
- Excited state potential energy surfaces and their interactions in Fe(IV)=O active sites.Dalton transactions (Cambridge, England : 2003) · 2014Article
- Direct observation of a nonheme iron(IV)-oxo complex that mediates aromatic C-F hydroxylation.Journal of the American Chemical Society · 2014Article
- Thioether-ligated iron(II) and iron(III)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere.Dalton transactions (Cambridge, England : 2003) · 2014Article
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Authors and funding
8 authors at 3 institutions in 3 countries.
Funding
Abstract
The new ligand N3Py(amide)SR and its Fe(II) complex [Fe(II)(N3Py(amide)SR)](BF4)2 (1) are described. Reaction of 1 with PhIO at -40 °C gives metastable [Fe(IV)(O)(N3Py(amide)SR)](2+) (2), containing a sulfide ligand and a single amide H-bond donor in proximity to the terminal oxo group. Direct evidence for H-bonding is seen in a structural analogue, [Fe(II)(Cl)(N3Py(amide)SR)](BF4)2 (3). Complex 2 exhibits rapid O-atom transfer (OAT) toward external sulfide substrates, but no intramolecular OAT. However, direct S-oxygenation does occur in the reaction of 1 with mCPBA, yielding sulfoxide-ligated [Fe(II)(N3Py(amide)S(O)R)](BF4)2 (4). Catalytic OAT with 1 was also observed.
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