ArticleOrganometallics2012
Mechanistic Studies of Azaphilic versus Carbophilic Activation by Gold(I) in the Gold/Palladium Dual-Catalyzed Rearrangement of Alkenyl Vinyl Aziridines.
Article in Organometallics, 2012. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
8 citing papers in PubMed, 72 citations in OpenAlex.
- Phosphinoindenyl and phosphazidoindenyl complexes of lanthanum and samarium: synthesis, characterisation, and hydroamination catalysis.Dalton transactions (Cambridge, England : 2003) · 2022Article
- Bimetallic catalysis for C-C and C-X coupling reactions.Chemical science · 2017Review
- Kinetic Study of Carbophilic Lewis Acid Catalyzed Oxyboration and the Noninnocent Role of Sodium Chloride.Organometallics · 2016Article
- Gold(I) and Gold(III) Complexes of Cyclic (Alkyl)(amino)carbenes.Organometallics · 2015Article
- Selectivity, Compatibility, Downstream Functionalization, and Silver Effect in the Gold and Palladium Dual-Catalytic Synthesis of Lactones.Organometallics · 2014Article
- Mechanistic Studies of Gold and Palladium Cooperative Dual-Catalytic Cross-Coupling Systems.ACS catalysis · 2014Article
- Ring expansion of vinylaziridines through the strain-release pericyclic reaction: recent developments and applications.Molecules (Basel, Switzerland) · 2013Article
- Preparation and ring-opening reactions of N-diphenylphosphinyl vinyl aziridines.Beilstein journal of organic chemistry · 2013Article
Corrections and comments
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
Abstract
A vinyl aziridine activation strategy cocatalyzed by palladium(0) and a gold(I) Lewis acid has been developed. This rearrangement installs a C-C and a C-N bond in one synthetic step to form pyrrolizidine and indolizidine products. Two proposed mechanistic roles for the gold cocatalyst were considered: (1) carbophilic gold catalysis or (2) azaphilic gold catalysis. Mechanistic studies support an azaphilic Lewis acid activation of the aziridine over a carbophilic Lewis acid activation of the alkene.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.