ArticleJournal of the American Chemical Society2014
Tungsten-catalyzed asymmetric epoxidation of allylic and homoallylic alcohols with hydrogen peroxide.
Article in Journal of the American Chemical Society, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
- Carbonaceous supports for Schiff base metal complexes: Strategies for enhanced catalytic efficiency.iScience · 2026Review
- Enantioselective Route to Terminal 2,3-Epoxy Tosylates Enabled by Cooperative Organocatalytic Desymmetrization of 2-Substituted Glycerol Derivatives.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- A Comparative Study ofMolecules (Basel, Switzerland) · 2025Article
- Article
- Natural Product-Oriented Photo-Induced Denitrogenative Annulations of 1-Alkenylbenzotriazoles.Molecules (Basel, Switzerland) · 2023Article
- Intensification of Double Kinetic Resolution of Chiral Amines and Alcohols via Chemoselective Formation of a Carbonate-Enzyme Intermediate.Molecules (Basel, Switzerland) · 2022Article
- Vanadium-doped phosphomolybdic acids as catalysts for geraniol oxidation with hydrogen peroxide.RSC advances · 2022Article
- Vanadium-doped sodium phosphomolybdate salts as catalysts in the terpene alcohols oxidation with hydrogen peroxide.RSC advances · 2021Article
- Asymmetric Total Synthesis of 19,20-Epoxydocosapentaenoic Acid, a Bioactive Metabolite of Docosahexaenoic Acid.The Journal of organic chemistry · 2019Article
- Direct N-O bond formationChemical science · 2019Article
- Cu-catalyzed cross-coupling reactions of vinyl epoxide with organoboron compounds: access to homoallylic alcohols.RSC advances · 2018Article
- One-pot synthesis of (-)-Ambrox.Scientific reports · 2016Article
- Rearrangements of organic peroxides and related processes.Beilstein journal of organic chemistry · 2016Review
- Synthesis of virtually enantiopure aminodiols with three adjacent stereogenic centers by epoxidation and ring-opening.Organic & biomolecular chemistry · 2015Article
- Tungsten-catalyzed regio- and enantioselective aminolysis of trans-2,3-epoxy alcohols: an entry to virtually enantiopure amino alcohols.Angewandte Chemie (International ed. in English) · 2014Article
- Tungsten-catalyzed regioselective and stereospecific ring opening of 2,3-epoxy alcohols and 2,3-epoxy sulfonamides.Journal of the American Chemical Society · 2014Article
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Authors and funding
2 authors.
Funding
Abstract
A simple, efficient, and environmentally friendly asymmetric epoxidation of primary, secondary, tertiary allylic, and homoallylic alcohols has been accomplished. This process was promoted by a tungsten-bishydroxamic acid complex at room temperature with the use of aqueous 30% H2O2 as oxidant, yielding the products in 84-98% ee.
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