Evidence map›Paper›PMID 24393099›Full record

ArticleJournal of the American Chemical Society2014

Regenerative glycosylation under nucleophilic catalysis.

Swati S Nigudkar, Keith J Stine, Alexei V Demchenko

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.

0numbers the graph read from it
0cells of the map it votes in
19citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

19 citing papers in PubMed.

  1. Isothiourea - catalyzed α-selective glycosylations.Chemical communications (Cambridge, England) · 2025
    Article
  2. Article
  3. Directed SJournal of the American Chemical Society · 2023
    Article
  4. Review
  5. Article
  6. Article
  7. Article
  8. Defining the Scope of the Acid-Catalyzed Glycosidation of Glycosyl Bromides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020
    Article
  9. Bromine-Promoted Glycosidation of Conformationally Superarmed Thioglycosides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2019
    Article
  10. Recent Developments in Stereoselective Chemical Glycosylation.Asian journal of organic chemistry · 2019
    Article
  11. Phenanthroline-Catalyzed Stereoretentive Glycosylations.Angewandte Chemie (International ed. in English) · 2019
    Article
  12. Article
  13. Article
  14. Review
  15. Regenerative Glycosylation.The Journal of organic chemistry · 2018
    Article
  16. Article
  17. Article
  18. A versatile glycosylation strategyChemical science · 2016
    Article
  19. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Swati S NigudkarDepartment of Chemistry and Biochemistry, University of Missouri-St. Louis , One University Boulevard, St. Louis, Missouri 63121, United States.
Keith J Stine
Alexei V Demchenko

Funding

Development and Application of Surface-Tethered Iterative Carbohydrate SynthesisR01GM090254 · NIGMS · UNIVERSITY OF MISSOURI-ST. LOUIS · PI STINE, KEITH J. · 2009 to 2012
$1.1M
New strategies for expeditious oligosaccharide synthesisR15GM077170 · NIGMS · UNIVERSITY OF MISSOURI-ST. LOUIS · PI DEMCHENKO, ALEXEI V · 2006 to 2011
$748k
NIGMS NIH HHS GM077170NIGMS NIH HHS GM090254NIGMS NIH HHS R01 GM090254NIGMS NIH HHS R15 GM077170
6 · The paper itself

Abstract

This article describes 3,3-difluoroxindole (HOFox)-mediated glycosylation. The uniqueness of this approach is that both the in situ synthesis of 3,3-difluoro-3H-indol-2-yl (OFox) glycosyl donors and activation thereof can be conducted in a regenerative fashion as is a typical reaction performed under nucleophilic catalysis. Only a catalytic amount of the OFox imidate donor and a Lewis acid activator are present in the reaction medium. The OFox imidate donor is constantly regenerated upon its consumption until glycosyl acceptor has reacted.

Indexed as

CatalysisGlycosylationIndolesOxindolesOxygen3,3-difluoroxindoleIndolesOxindolesOxygen

Identifiers

PMID24393099
PMCPMC3933924

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.