Evidence map›Paper›PMID 24376910›Full record

ArticleChemical science2014

Mechanism of Electrophilic Fluorination with Pd(IV): Fluoride Capture and Subsequent Oxidative Fluoride Transfer

Jochen R Brandt, Eunsung Lee, Gregory B Boursalian, Tobias Ritter

Abstract read
In one paragraph

Article in Chemical science, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.

0numbers the graph read from it
0cells of the map it votes in
15citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

15 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Mechanism of the Aryl-F Bond-Forming Step from Bi(V) Fluorides.Journal of the American Chemical Society · 2022
    Article
  5. Article
  6. Article
  7. Article
  8. High-Valent NiMolecules (Basel, Switzerland) · 2020
    Review
  9. Article
  10. Article
  11. Review
  12. Late-stage [Chemical science · 2014
    Article
  13. Article
  14. Late-Stage Fluorination: From Fundamentals to Application.Organic process research & development · 2014
    Review
  15. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Jochen R BrandtDepartment of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, United States.
Eunsung LeeDepartment of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, United States.
Gregory B BoursalianDepartment of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, United States.
Tobias RitterDepartment of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, United States.

Funding

Organometallic Chemistry for Applications in Biomedical SciencesR01GM088237 · NIGMS · HARVARD UNIVERSITY · PI RITTER, TOBIAS · 2010 to 2016
$2.5M
New Chemical Methods for Molecular Imaging to Impact Clinical CareR01EB013042 · NIBIB · HARVARD UNIVERSITY · PI HOOKER, JACOB M., RITTER, TOBIAS · 2011 to 2014
$2.1M
NIBIB NIH HHS R01 EB013042NIGMS NIH HHS R01 GM088237
6 · The paper itself

Abstract

Electrophilic fluorinating reagents derived from fluoride are desirable for the synthesis of

Identifiers

PMID24376910
PMCPMC3870902

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.