Micro-flow synthesis and structural analysis of sterically crowded diimine ligands with five aryl rings.

Shinichiro Fuse, Nobutake Tanabe, Akio Tannna, Yohei Konishi, Takashi Takahashi

Abstract read

In one paragraph

Article in Beilstein journal of organic chemistry, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

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0cells of the map it votes in

2citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

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Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

Total synthesis of feglymycin based on a linear/convergent hybrid approach using micro-flow amide bond formation.Nature communications · 2016
Article
Efficient amide bond formation through a rapid and strong activation of carboxylic acids in a microflow reactor.Angewandte Chemie (International ed. in English) · 2014
Article

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Shinichiro FuseDepartment of Applied Chemistry, Tokyo Institute of Technology, 2-12-1, Ookayama, Meguro-ku, Tokyo, 152-8552, Japan.

Nobutake TanabeDepartment of Applied Chemistry, Tokyo Institute of Technology, 2-12-1, Ookayama, Meguro-ku, Tokyo, 152-8552, Japan.

Akio TannnaMitsubishi Chemical Croup, Science and Technology Research Center, Inc., 1000 Kamoshida-cho, Aoba-ku, Yokohama 227-8502, Japan.

Yohei KonishiMitsubishi Chemical Croup, Science and Technology Research Center, Inc., 1000 Kamoshida-cho, Aoba-ku, Yokohama 227-8502, Japan.

Takashi TakahashiDepartment of Applied Chemistry, Tokyo Institute of Technology, 2-12-1, Ookayama, Meguro-ku, Tokyo, 152-8552, Japan.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Sterically crowded diimine ligands with five aryl rings were prepared in one step in good yields using a micro-flow technique. X-ray crystallographic analysis revealed the detailed structure of the bulky ligands. The nickel complexes prepared from the ligands exerted high polymerization activity in the ethylene homopolymerization and copolymerization of ethylene with polar monomers.

Indexed as

amidine formationdiimineflow chemistrypolymerization

Identifiers

PMID24367397

DOI10.3762/bjoc.9.268

PMCPMC3869212

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