ArticleEuropean journal of organic chemistry2013
Beyond the Divinyl Ketone: Innovations in the Generation and Nazarov Cyclization of Pentadienyl Cation Intermediates.
Article in European journal of organic chemistry, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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Who cites it
18 citing papers in PubMed.
- Mild and catalytic electrocyclizations of heptatrienyl anions.Chemical science · 2024Article
- Catalytic Enantioselective Protonation of Gold Enolates Enabled by Cooperative Gold(I) Catalysis.Journal of the American Chemical Society · 2024Article
- Computational insights into the mechanisms and origins of switchable selectivity in gold(i)-catalyzed annulation of ynamides with isoxazolesRSC advances · 2023Article
- Asymmetric Gold(I)-Catalyzed Tandem Hydroarylation-Nazarov Cyclization: Enantioselective Access to Cyclopentenones.Angewandte Chemie (International ed. in English) · 2022Article
- Correction: Palladium-catalysed 5-Chemical science · 2020Article
- Pentannulation of N-heterocycles by a tandem gold-catalyzed [3,3]-rearrangement/Nazarov reaction of propargyl ester derivatives: a computational study on the crucial role of the nitrogen atom.Beilstein journal of organic chemistry · 2020Article
- Protonation of Curcumin Triggers Sequential Double Cyclization in the Gas-Phase: An Electrospray Mass Spectrometry and DFT Study.International journal of mass spectrometry · 2019Article
- Gold-catalyzed [4+3]- and [4+2]-annulations of 3-en-1-ynamides with isoxazolesChemical science · 2018Article
- Asymmetric syntheses of 8-oxabicyclo[3,2,1]octane and 11-oxatricyclo[5.3.1.0]undecane from glycals.Chemical science · 2017Article
- Nazarov cyclization of 1,4-pentadien-3-ols: preparation of cyclopenta[b]indoles and spiro[indene-1,4'-quinoline]s.Chemical communications (Cambridge, England) · 2016Article
- The first intermolecular interrupted imino-Nazarov reaction: expeditious access to carbocyclic nucleoside analogues.Chemical science · 2016Article
- Enantioselective Nazarov Cyclization Catalyzed by a Cinchona Alkaloid Derivative.Tetrahedron letters · 2015Article
- Gold(I)-catalyzed dearomative Rautenstrauch rearrangement: enantioselective access to cyclopenta[b]indoles.Journal of the American Chemical Society · 2015Article
- No acid required: 4π and 6π electrocyclization reactions of dienyl diketones for the synthesis of cyclopentenones and 2H-Pyrans.The Journal of organic chemistry · 2014Article
- Synthesis of (±)-tetrapetalone A-Me aglycon.Angewandte Chemie (International ed. in English) · 2014Article
- Cationic cyclizations and rearrangements promoted by a heterogeneous gold catalyst.Organic letters · 2014Article
- Diastereospecific nazarov cyclization of fully substituted dienones: generation of vicinal all-carbon-atom quaternary stereocenters.Angewandte Chemie (International ed. in English) · 2013Article
- The Piancatelli rearrangement: new applications for an intriguing reaction.Molecules (Basel, Switzerland) · 2013Review
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3 authors.
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Abstract
The requirement for new strategies for synthesizing five-membered carbocycles has driven an expansion in the study of the Nazarov cyclization. This renewed interest in the reaction has led to the discovery of several interesting new methods for generating the pentadienyl cation intermediate central to the cyclization. Methods reviewed include carbon-heteroatom ionization, functionalization of a double bond, nucleophilic addition, or electrocyclic ring opening. Additional variations employ unconventional substrates to produce novel pentacycles, such as the iso- and imino-Nazarov. Herein, we provide an overview of these unconventional, yet highly useful versions of the Nazarov cyclization.
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