ArticleJournal of the American Chemical Society2013
Heterometallic triiron-oxo/hydroxo clusters: effect of redox-inactive metals.
Article in Journal of the American Chemical Society, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
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Who cites it
28 citing papers in PubMed.
- Prediction of perovskite oxygen vacancies for oxygen electrocatalysis at different temperatures.Nature communications · 2024Article
- Redox Processes Involving Oxygen: The Surprising Influence of Redox-Inactive Lewis Acids.JACS Au · 2024Review
- Structural distortion by alkali metal cations modulates the redox and electronic properties of CeChemical science · 2023Article
- Altering Oxygen Binding by Redox-Inactive Metal Substitution to Control Catalytic Activity: Oxygen Reduction on Manganese Oxide Nanoparticles as a Model System.Angewandte Chemie (International ed. in English) · 2023Article
- Electronic Consequences of Ligand Substitution at Heterometal Centers in Polyoxovanadium Clusters: Controlling the Redox Properties through Heterometal Coordination Number.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Effects of Noncovalent Interactions on High-Spin Fe(IV)-Oxido Complexes.Journal of the American Chemical Society · 2020Article
- Redox Tuning via Ligand-Induced Geometric Distortions at a YMnInorganic chemistry · 2019Article
- Activation of a Non-Heme FeAngewandte Chemie (International ed. in English) · 2019Article
- Effects of Lewis Acidic Metal Ions (M) on Oxygen-Atom Transfer Reactivity of Heterometallic MnInorganic chemistry · 2019Article
- Thermodynamics of Proton and Electron Transfer in Tetranuclear Clusters with Mn-OHJournal of the American Chemical Society · 2018Article
- Nitric oxide activation facilitated by cooperative multimetallic electron transfer within an iron-functionalized polyoxovanadate-alkoxide cluster.Chemical science · 2018Article
- A Thermodynamic Model for Redox-Dependent Binding of Carbon Monoxide at Site-Differentiated, High Spin Iron Clusters.Journal of the American Chemical Society · 2018Article
- Incorporation of redox-inactive cations promotes iron catalyzed aerobic C-H oxidation at mild potentials.Chemical science · 2018Article
- Models for Unsymmetrical Active Sites in Metalloproteins: Structural, Redox, and Magnetic Properties of Bimetallic Complexes with MInorganic chemistry · 2017Article
- Tetranuclear Fe Clusters with a Varied Interstitial Ligand: Effects on the Structure, Redox Properties, and Nitric Oxide Activation.Inorganic chemistry · 2017Article
- Selectivity of C-H versus C-F Bond Oxygenation by Homo- and Heterometallic FeChemistry (Weinheim an der Bergstrasse, Germany) · 2017Article
- A CaMnChemical communications (Cambridge, England) · 2017Article
- Accelerated Oxygen Atom Transfer and C-H Bond Oxygenation by Remote Redox Changes in FeAngewandte Chemie (International ed. in English) · 2017Article
- Substituting Fe for two of the four Mn ions in photosystem II-effects on water-oxidation.Journal of bioenergetics and biomembranes · 2016Article
- Photocatalytic Oxygenation of Substrates by Dioxygen with Protonated Manganese(III) Corrolazine.Inorganic chemistry · 2016Article
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Abstract
A series of tetranuclear oxo/hydroxo clusters comprised of three Fe centers and a redox-inactive metal (M) of various charge is reported. Crystallographic studies show an unprecedented Fe3M(μ4-O)(μ2-OH) core that remains intact upon changing M or the oxidation state of iron. Electrochemical studies reveal that the reduction potentials (E1/2) span a window of 500 mV and depend upon the Lewis acidity of M. Using the pKa of the M-aqua complex as a measure of Lewis acidity, these compounds display a linear dependence between E1/2 and acidity, with a slope of ∼70 mV per pKa unit. The current study of [Fe3MO(OH)] and previous ones of [Mn3MOn] (n = 2,4) moieties support the generality of the above relationship between the reduction potentials of heterometallic oxido clusters and the Lewis acidity of incorporated cations, as applied to clusters of different redox-active metals.
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