ArticleOrganic letters2014
Palladium-catalyzed α-arylation of benzylic phosphine oxides.
Article in Organic letters, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- Article
- Cyclopentyl Methyl Ether: An Elective Ecofriendly Ethereal Solvent in Classical and Modern Organic Chemistry.ChemSusChem · 2019Review
- Straightforward Synthesis of Bifunctional Phosphorus Phenols via Phosphination of In Situ GeneratedMolecules (Basel, Switzerland) · 2018Article
- Tandem C(spAdvanced synthesis & catalysis · 2016Article
- Palladium-Catalyzed Benzylic Arylation of Pyridylmethyl Silyl Ethers: One-Pot Synthesis of Aryl(pyridyl)methanols.Organic letters · 2016Article
- Chemoselective Palladium-Catalyzed Deprotonative Arylation/[1,2]-Wittig Rearrangement of Pyridylmethyl Ethers.Chemical science · 2016Article
- Palladium-Catalyzed Benzylic C-H Arylation of Azaarylmethylamines.Organic letters · 2015Article
- Palladium-catalyzed C(sp(3))-H Arylation of N-Boc benzylalkylamines via a deprotonative cross-coupling process.Chemistry (Weinheim an der Bergstrasse, Germany) · 2015Article
- Synthesis of triarylmethanols via tandem arylation/oxidation of diarylmethanes.Tetrahedron letters · 2015Article
- Palladium-catalyzed α-arylation of aryl acetic acid derivatives via dienolate intermediates with aryl chlorides and bromides.Organic letters · 2015Article
- Reversed-Polarity Synthesis of Diaryl Ketones through Palladium-Catalyzed Direct Arylation of 2-Aryl-1,3-dithianes.Advanced synthesis & catalysis · 2014Article
- Room-temperature palladium-catalyzed direct 2-arylation of benzoxazoles with aryl and heteroaryl bromides.Chemical communications (Cambridge, England) · 2014Article
- NiXantphos: a deprotonatable ligand for room-temperature palladium-catalyzed cross-couplings of aryl chlorides.Journal of the American Chemical Society · 2014Article
- Palladium-catalyzed α-arylation of benzylic phosphonates.Organic letters · 2014Article
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3 authors.
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Abstract
A novel approach to prepare diarylmethyl phosphine oxides from benzyl phosphine oxides via deprotonative cross-coupling processes (DCCP) is reported. The optimization of the reaction was guided by High-Throughput Experimentation (HTE) techniques. The Pd(OAc)2/Xantphos-based catalyst enabled the reaction between benzyl diphenyl or dicyclohexyl phosphine oxide derivatives and aryl bromides in good to excellent yields (51-91%).
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