ArticleThe journal of physical chemistry letters2013
Imaging Electric Fields in SERS and TERS Using the Vibrational Stark Effect.
Article in The journal of physical chemistry letters, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
What it found
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Who cites it
17 citing papers in PubMed.
- Ultrasensitive SERS detectionThe Analyst · 2026Article
- The Impact of Electric Fields on Processes at Electrode Interfaces.Chemical reviews · 2025Review
- Effects of Cosolvent on the Intermolecular Interactions between an Analyte and a Gold Nanostar Surface Studied Using SERS.The journal of physical chemistry. C, Nanomaterials and interfaces · 2024Article
- Local electric field in nanocavities dictates the vibrational relaxation dynamics of interfacial molecules.Chemical science · 2024Article
- Large negative differential conductance and its transformation in a single radical molecule.Chemical science · 2024Article
- Investigating the Role of Plasmonics in Electrospun Fibers by Combined Photothermal Heterodyne Imaging and Raman Measurements.The journal of physical chemistry. C, Nanomaterials and interfaces · 2024Article
- Selective Analysis of Redox Processes at the Electrode Interface with Time-Resolved Raman Spectroscopy.Langmuir : the ACS journal of surfaces and colloids · 2023Article
- Ultrasensitive Optical Fingerprinting of Biorelevant Molecules by Means of SERS-Mapping on Nanostructured Metasurfaces.Biosensors · 2022Article
- Label-Free Super-Resolution Imaging Techniques.Annual review of analytical chemistry (Palo Alto, Calif.) · 2022Review
- Redox Replacement of Silver on MOF-Derived Cu/C Nanoparticles on Gas Diffusion Electrodes for Electrocatalytic COChemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- A Versatile DNA Origami-Based Plasmonic Nanoantenna for Label-Free Single-Molecule Surface-Enhanced Raman Spectroscopy.ACS nano · 2021Article
- From SERS to TERS and Beyond: Molecules as Probes of Nanoscopic Optical Fields.The journal of physical chemistry. C, Nanomaterials and interfaces · 2020Article
- Resonant tip-enhanced Raman scattering by CdSe nanocrystals on plasmonic substrates.Nanoscale advances · 2020Article
- Microscopy with a single-molecule scanning electrometer.Science advances · 2018Article
- Detection of electron tunneling across plasmonic nanoparticle-film junctions using nitrile vibrations.Physical chemistry chemical physics : PCCP · 2017Article
- Experimental correlation of electric fields and Raman signals in SERS and TERS.Proceedings of SPIE--the International Society for Optical Engineering · 2015Article
- Alkyl-Nitrile Adlayers as Probes of Plasmonically Induced Electric Fields.Chemical science · 2015Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
Electric fields associated with Raman enhancements are typically inferred from changes in the observed scattering intensity. Here we use the vibrational Stark effect from a nitrile reporter to determine the electric field dependent frequency shift of cyanide (CN) on a gold (Au) surface. Electroplated Au surfaces with surface enhanced Raman (SERS) activity exhibit larger Stark shifts near the edge and in areas with large roughness. The Stark shift is observed to correlate with intensity of a co-adsorbed thiophenol molecule. Gap-mode Tip enhanced Raman scattering (TERS), using a Au nanoparticle tip, show dramatic shifts in the CN stretch that correlate to enhancement factors of 10
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.