ArticleBeilstein journal of organic chemistry2013
Synthesis of axially chiral gold complexes and their applications in asymmetric catalyses.
Article in Beilstein journal of organic chemistry, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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5 citing papers in PubMed.
- Origins of unique gold-catalysed chemo- and site-selective C-H functionalization of phenols with diazo compounds.Chemical science · 2016Article
- Mechanism of the Transmetalation of Organosilanes to Gold.ChemistryOpen · 2016Article
- When Phosphosugars Meet Gold: Synthesis and Catalytic Activities of Phostones and Polyhydroxylated Phosphonite Au(I) Complexes.Molecules (Basel, Switzerland) · 2015Article
- Enantioselective gold-catalyzed intermolecular [2+2]Chemical science · 2015Article
- Asymmetric gold-catalyzed lactonizations in water at room temperature.Angewandte Chemie (International ed. in English) · 2014Article
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3 authors.
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Abstract
Several novel chiral N-heterocyclic carbene and phosphine ligands were prepared from (S)-BINOL. Moreover, their ligated Au complexes were also successfully synthesized and characterized by X-ray crystal diffraction. A weak gold-π interaction between the Au atom and the aromatic ring in these gold complexes was identified. Furthermore, we confirmed the formation of a pair of diastereomeric isomers in NHC gold complexes bearing an axially chiral binaphthyl moiety derived from the hindered rotation around C-C and C-N bonds. In the asymmetric intramolecular hydroamination reaction most of these chiral Au(I) complexes showed good catalytic activities towards olefins tethered with a NHTs functional group to give the corresponding product in moderate yields and up to 29% ee.
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