ArticleNature chemistry2013
Water vibrations have strongly mixed intra- and intermolecular character.
Article in Nature chemistry, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 61 papers.
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Who cites it
61 citing papers in PubMed.
- Catalyst-directed vibrational frequency disparity for isotopologue sieving in CONature chemistry · 2026Article
- The Origin of the Frequency-Dependence of OH Stretch Vibrational Lifetimes in Liquid Water.The journal of physical chemistry letters · 2026Article
- Molecular Dynamics-Instantaneous Frequencies of Molecules Method to Address the Performance of Classical and Rigid Water Force Fields.The journal of physical chemistry. B · 2026Article
- Real-time tracking of the intramolecular vibrational dynamics of liquid water.Communications chemistry · 2026Article
- Reevaluating Anomalous Electric Fields at the Air-Water Interface: A Surface-Specific Spectroscopic Survey.Journal of the American Chemical Society · 2025Article
- Theoretical and quantum mechanical deconstruction of vibrational energy transfer pathways modified by collective vibrational strong coupling.Nature communications · 2025Article
- Article
- Real-TimeAnalytical chemistry · 2025Article
- Effect of magnetized water on the fundamental grouting properties of cement grout under varying magnetization conditions.Scientific reports · 2025Article
- Dynamic anti-correlations of water hydrogen bonds.Nature communications · 2024Article
- Optically accessible long-lived electronic biexcitons at room temperature in strongly coupled H- aggregates.Nature communications · 2024Article
- Molecular dynamics simulation study of water structure and dynamics on the gold electrode surface with adsorbed 4-mercaptobenzonitrile.The Journal of chemical physics · 2024Article
- Unified picture of vibrational relaxation of OH stretch at the air/water interface.Nature communications · 2024Article
- Femtosecond Electron-Transfer Dynamics across the DThe journal of physical chemistry. C, Nanomaterials and interfaces · 2023Article
- Breaking Barriers in Ultrafast Spectroscopy and Imaging Using 100 kHz Amplified Yb-Laser Systems.Accounts of chemical research · 2023Article
- Combinational Vibration Modes in HThe journal of physical chemistry. B · 2023Article
- Increasing Pump-Probe Signal toward Asymptotic Limits.The journal of physical chemistry. B · 2023Review
- Two-dimensional infrared-Raman spectroscopy as a probe of water's tetrahedrality.Nature communications · 2023Article
- Probing the Molecular Dynamics of Aqueous Binary Solutions with THz Time-Domain Ellipsometry.Sensors (Basel, Switzerland) · 2023Article
- Towards time resolved characterization of electrochemical reactions: electrochemically-induced Raman spectroscopy.Chemical science · 2022Article
1 more citing papers are in PubMed but not listed here.
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The ability of liquid water to dissipate energy efficiently through ultrafast vibrational relaxation plays a key role in the stabilization of reactive intermediates and the outcome of aqueous chemical reactions. The vibrational couplings that govern energy relaxation in H2O remain difficult to characterize because of the limitations of current methods to visualize inter- and intramolecular motions simultaneously. Using a new sub-70 fs broadband mid-infrared source, we performed two-dimensional infrared, transient absorption and polarization anisotropy spectroscopy of H2O by exciting the OH stretching transition and characterizing the response from 1,350 cm(-1) to 4,000 cm(-1). These spectra reveal vibrational transitions at all frequencies simultaneous to the excitation, including pronounced cross-peaks to the bend vibration and a continuum of induced absorptions to combination bands that are not present in linear spectra. These observations provide evidence for strong mixing of inter- and intramolecular vibrations in liquid H2O, and illustrate the shortcomings of traditional relaxation models.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.