ArticleInorganic chemistry2013
Studies of iron(III) porphyrinates containing silanethiolate ligands.
Article in Inorganic chemistry, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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3 citing papers in PubMed.
- Detoxification of hydrogen sulfide by synthetic heme model compounds.Scientific reports · 2024Article
- Carboxyl activation via silylthioesterification: one-pot, two-step amidation of carboxylic acids catalyzed by non-metal ammonium salts.Tetrahedron letters · 2015Article
- Chemically reversible reactions of hydrogen sulfide with metal phthalocyanines.Inorganic chemistry · 2014Article
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4 authors.
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Abstract
The chemistry of several iron(III) porphyrinates containing silanethiolate ligands is described. The complexes are prepared by protonolysis reactions of silanethiols with the iron(III) precursors, [Fe(OMe)(TPP)] and [Fe(OH)(H2O)(TMP)] (TPP = dianion of meso-tetraphenylporphine; TMP = dianion of meso-tetramesitylporphine). Each of the compounds has been fully characterized in solution and the solid state. The stability of the silanethiolate complexes versus other iron(III) porphyrinate complexes containing sulfur-based ligands allows for an examination of their reactivity with several biologically relevant small molecules including H2S, NO, and 1-methylimidazole. Electrochemically, the silanethiolate complexes display a quasi-reversible one-electron oxidation event at potentials higher than that observed for an analogous arenethiolate complex. The behavior of these complexes versus other sulfur-ligated iron(III) porphyrinates is discussed.
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