ArticleThe Journal of chemical physics2013
Fully absorptive 3D IR spectroscopy using a dual mid-infrared pulse shaper.
Article in The Journal of chemical physics, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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Who cites it
6 citing papers in PubMed.
- Neumann's principle based eigenvector approach for deriving non-vanishing tensor elements for nonlinear optics.The Journal of chemical physics · 2022Article
- Phase stable, shot-to-shot measurement of third- and fifth-order two-quantum correlation spectra using a pulse shaper in the pump-probe geometry.The Journal of chemical physics · 2022Article
- Shot-to-shot 2D IR spectroscopy at 100 kHz using a Yb laser and custom-designed electronics.Optics express · 2020Article
- Direct observation of multistep energy transfer in LHCII with fifth-order 3D electronic spectroscopy.Nature communications · 2015Article
- Applications of two-dimensional infrared spectroscopy.The Analyst · 2015Review
- Testing for memory-free spectroscopic coordinates by 3D IR exchange spectroscopy.Proceedings of the National Academy of Sciences of the United States of America · 2014Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
This paper presents the implementation of 3D IR spectroscopy by adding a second pump beam to a two-beam 2D IR spectrometer. An independent mid-IR pulse shaper is used for each pump beam, which can be programmed to collect its corresponding dimension in either the frequency or time-domains. Due to the phase matching geometry employed here, absorptive 3D IR spectra are automatically obtained, since all four of the rephasing and non-rephasing signals necessary to generate absorptive spectra are collected simultaneously. Phase cycling is used to isolate the fifth-order from the third-order signals. The method is demonstrated on tungsten hexacarbonyl (W(CO)6) and dicarbonylacetylacetonato rhodium (I), for which the eigenstates are extracted up to the third excited state. Pulse shaping affords a high degree of control over 3D IR experiments by making possible mixed time- and frequency-domain experiments, fast data acquisition and straightforward implementation.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.