Evidence map›Paper›PMID 24091804›Full record

ArticleJournal of fluorescence2014

Fluorescence Turn on Sensor for Sulfate Ion in Aqueous Medium Using Tripodal-Cu(2+) Ensemble.

Md Najbul Hoque, Arghya Basu, Gopal Das

Abstract read
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Article in Journal of fluorescence, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Md Najbul HoqueDepartment of Chemistry, Indian Institute of Technology Guwahati, Assam, 781 039, India.
Arghya BasuDepartment of Chemistry, Indian Institute of Technology Guwahati, Assam, 781 039, India.
Gopal DasDepartment of Chemistry, Indian Institute of Technology Guwahati, Assam, 781 039, India. gdas@iitg.ernet.in.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

We report the selective recognition of sulfate anion in aqueous medium at biological pH 7.2 over the other interfering anions based on naphthoic acid bearing tripodal ligand by applying fluorescence turn off -on mechanism. The carboxylic acid groups in the ligand enhance the solubility in water and enable it to form complex with copper salt. Thus formed L-Cu2+ ensemble quench the fluorescence of the parent ligand and in turn recognize sulfate anion via revival of fluorescence intensity. The 1:2 stoichiometry was confirmed by ESI mass spectral data and Job's plot. The average binding constant was found to be 6.2×10(8) M(-2).

Indexed as

FluorescenceUltrasonicsCopperLimit of DetectionSulfatesWaterCopperSulfatesWaterAqueous mediumFluorescence turn off-on sensorNaphthoic acid based tripodalSulfate sensing

Identifiers

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.